Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalyst...
| Main Authors: | , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2019-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-018-08063-3 |
| _version_ | 1819036086041575424 |
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| author | Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán |
| author_facet | Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán |
| author_sort | Vicent Lloret |
| collection | DOAJ |
| description | Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalysts for the alkylation of nucleophiles with esters. |
| first_indexed | 2024-12-21T07:59:55Z |
| format | Article |
| id | doaj.art-28a596c09abf4115927d5c20f93f25ca |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-21T07:59:55Z |
| publishDate | 2019-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-28a596c09abf4115927d5c20f93f25ca2022-12-21T19:10:55ZengNature PortfolioNature Communications2041-17232019-01-0110111110.1038/s41467-018-08063-3Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with estersVicent Lloret0Miguel Ángel Rivero-Crespo1José Alejandro Vidal-Moya2Stefan Wild3Antonio Doménech-Carbó4Bettina S. J. Heller5Sunghwan Shin6Hans-Peter Steinrück7Florian Maier8Frank Hauke9Maria Varela10Andreas Hirsch11Antonio Leyva-Pérez12Gonzalo Abellán13Department of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Instituto de Tecnología Química, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones CientíficasInstituto de Tecnología Química, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones CientíficasDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Departamento de Química Analítica, Universidad de ValenciaChair of Physical Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Chair of Physical Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Chair of Physical Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Chair of Physical Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Department of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Departamento de Física de Materiales, Universidad Complutense de Madrid, Instituto Pluridisciplinar, Instituto de Magnetismo AplicadoDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Instituto de Tecnología Química, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones CientíficasDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalysts for the alkylation of nucleophiles with esters.https://doi.org/10.1038/s41467-018-08063-3 |
| spellingShingle | Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters Nature Communications |
| title | Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
| title_full | Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
| title_fullStr | Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
| title_full_unstemmed | Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
| title_short | Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters |
| title_sort | few layer 2d pnictogens catalyze the alkylation of soft nucleophiles with esters |
| url | https://doi.org/10.1038/s41467-018-08063-3 |
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