Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)]
The title compound, [Cd(C8H8O5)(C3H4N2)2]n, was synthesized by the reaction of 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The CdII atom is seven-coordinated in a distorted pentagonal-bipyramidal configuration by five O atoms from carboxylate groups of three...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809021801 |
| _version_ | 1818907593283731456 |
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| author | Na Wang Yan-Jun Wang Qiu-Yue Lin |
| author_facet | Na Wang Yan-Jun Wang Qiu-Yue Lin |
| author_sort | Na Wang |
| collection | DOAJ |
| description | The title compound, [Cd(C8H8O5)(C3H4N2)2]n, was synthesized by the reaction of 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The CdII atom is seven-coordinated in a distorted pentagonal-bipyramidal configuration by five O atoms from carboxylate groups of three 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate ligands and two N atoms from two imidazole ligands. The crystal structure is stabilized by N—H...O and C—H...O hydrogen-bonding and C—H...π interactions. |
| first_indexed | 2024-12-19T21:57:35Z |
| format | Article |
| id | doaj.art-28a739b6cf1f4edca38ef5d405498ad7 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:57:35Z |
| publishDate | 2009-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-28a739b6cf1f4edca38ef5d405498ad72022-12-21T20:04:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m782m78210.1107/S1600536809021801Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)]Na WangYan-Jun WangQiu-Yue LinThe title compound, [Cd(C8H8O5)(C3H4N2)2]n, was synthesized by the reaction of 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The CdII atom is seven-coordinated in a distorted pentagonal-bipyramidal configuration by five O atoms from carboxylate groups of three 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate ligands and two N atoms from two imidazole ligands. The crystal structure is stabilized by N—H...O and C—H...O hydrogen-bonding and C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536809021801 |
| spellingShingle | Na Wang Yan-Jun Wang Qiu-Yue Lin Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)] Acta Crystallographica Section E |
| title | Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)] |
| title_full | Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)] |
| title_fullStr | Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)] |
| title_full_unstemmed | Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)] |
| title_short | Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)] |
| title_sort | poly bis 1h imidazole amp 956 3 7 oxabicyclo 2 2 1 heptane 2 3 dicarboxylato cadmium ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809021801 |
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