Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one
In the title compound, C13H10ClNOS2, the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chlorobenzylidene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.519 (13):0...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2015-12-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015022689 |
| _version_ | 1818971599507816448 |
|---|---|
| author | Rahhal El Ajlaoui El Mostapha Rakib Souad Mojahidi Mohamed Saadi Lahcen El Ammari |
| author_facet | Rahhal El Ajlaoui El Mostapha Rakib Souad Mojahidi Mohamed Saadi Lahcen El Ammari |
| author_sort | Rahhal El Ajlaoui |
| collection | DOAJ |
| description | In the title compound, C13H10ClNOS2, the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chlorobenzylidene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.519 (13):0.481 (13) ratio. A short intramolecular C—H...S interaction closes an S(6) ring. In the crystal, molecules are linked by π–π stacking interactions [centroid–centroid separation = 3.600 (15) Å], generating inversion dimers. |
| first_indexed | 2024-12-20T14:54:56Z |
| format | Article |
| id | doaj.art-28bf525f534741b493a8ff61049ef0e1 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T14:54:56Z |
| publishDate | 2015-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-28bf525f534741b493a8ff61049ef0e12022-12-21T19:36:53ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-12-017112o1012o101210.1107/S2056989015022689hb7551Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-oneRahhal El Ajlaoui0El Mostapha Rakib1Souad Mojahidi2Mohamed Saadi3Lahcen El Ammari4Laboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V de Rabat, Avenue Ibn Battouta, BP 1014, Rabat, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V de Rabat, Avenue Ibn Battouta, BP 1014, Rabat, MoroccoIn the title compound, C13H10ClNOS2, the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chlorobenzylidene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.519 (13):0.481 (13) ratio. A short intramolecular C—H...S interaction closes an S(6) ring. In the crystal, molecules are linked by π–π stacking interactions [centroid–centroid separation = 3.600 (15) Å], generating inversion dimers.http://scripts.iucr.org/cgi-bin/paper?S2056989015022689crystal structurerhodanine-based moleculespharmacological activitybiological activity1,3-thiazolidin-4-one |
| spellingShingle | Rahhal El Ajlaoui El Mostapha Rakib Souad Mojahidi Mohamed Saadi Lahcen El Ammari Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one Acta Crystallographica Section E: Crystallographic Communications crystal structure rhodanine-based molecules pharmacological activity biological activity 1,3-thiazolidin-4-one |
| title | Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_full | Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_fullStr | Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_full_unstemmed | Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_short | Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_sort | crystal structure of z 3 allyl 5 4 chlorobenzylidene 2 sulfanylidene 1 3 thiazolidin 4 one |
| topic | crystal structure rhodanine-based molecules pharmacological activity biological activity 1,3-thiazolidin-4-one |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015022689 |
| work_keys_str_mv | AT rahhalelajlaoui crystalstructureofz3allyl54chlorobenzylidene2sulfanylidene13thiazolidin4one AT elmostapharakib crystalstructureofz3allyl54chlorobenzylidene2sulfanylidene13thiazolidin4one AT souadmojahidi crystalstructureofz3allyl54chlorobenzylidene2sulfanylidene13thiazolidin4one AT mohamedsaadi crystalstructureofz3allyl54chlorobenzylidene2sulfanylidene13thiazolidin4one AT lahcenelammari crystalstructureofz3allyl54chlorobenzylidene2sulfanylidene13thiazolidin4one |