NiFe<sub>2</sub>O<sub>4</sub> Material on Carbon Paper as an Electrocatalyst for Alkaline Water Electrolysis Module

NiFe<sub>2</sub>O<sub>4</sub> material is grown on carbon paper (CP) with the hydrothermal method for use as electrocatalysts in an alkaline electrolyzer. NiFe<sub>2</sub>O<sub>4</sub> material is used as the anode and cathode catalysts (named NiFe(+)/...

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Main Authors: Ying-Chyi Wang, Shuo-En Yu, Yu-Lun Su, I-Chun Cheng, Yi-Cheng Chuang, Yong-Song Chen, Jian-Zhang Chen
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/15/1/62
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author Ying-Chyi Wang
Shuo-En Yu
Yu-Lun Su
I-Chun Cheng
Yi-Cheng Chuang
Yong-Song Chen
Jian-Zhang Chen
author_facet Ying-Chyi Wang
Shuo-En Yu
Yu-Lun Su
I-Chun Cheng
Yi-Cheng Chuang
Yong-Song Chen
Jian-Zhang Chen
author_sort Ying-Chyi Wang
collection DOAJ
description NiFe<sub>2</sub>O<sub>4</sub> material is grown on carbon paper (CP) with the hydrothermal method for use as electrocatalysts in an alkaline electrolyzer. NiFe<sub>2</sub>O<sub>4</sub> material is used as the anode and cathode catalysts (named NiFe(+)/NiFe(−) hereafter). The results are compared with those obtained using CP/NiFe as the anode and CP/Ru as the cathode (named NiFe)(+)/Ru(−) hereafter). During cell operation with NiFe(+)/Ru(−), the current density reaches 500 mA/cm<sup>2</sup> at a cell voltage of 1.79 V, with a specific energy consumption of 4.9 kWh/m<sup>3</sup> and an energy efficiency of 66.2%. In comparison, for NiFe(+)/NiFe(−), the current density reaches 500 mA/cm<sup>2</sup> at a cell voltage of 2.23 V, with a specific energy consumption of 5.7 kWh/m<sup>3</sup> and an energy efficiency of 56.6%. The Faradaic efficiency is 96–99%. With the current density fixed at 400 mA/cm<sup>2</sup>, after performing a test for 150 h, the cell voltage with NiFe(+)/Ru(−) increases by 0.167 V, whereas that with NiFe(+)/NiFe(−) decreases by only 0.010 V. Good, long-term stability is demonstrated.
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spelling doaj.art-28bfb24305404cab8196224ca110977b2024-01-26T17:43:43ZengMDPI AGMicromachines2072-666X2023-12-011516210.3390/mi15010062NiFe<sub>2</sub>O<sub>4</sub> Material on Carbon Paper as an Electrocatalyst for Alkaline Water Electrolysis ModuleYing-Chyi Wang0Shuo-En Yu1Yu-Lun Su2I-Chun Cheng3Yi-Cheng Chuang4Yong-Song Chen5Jian-Zhang Chen6Institute of Applied Mechanics, National Taiwan University, Taipei City 106319, TaiwanGraduate School of Advanced Technology, National Taiwan University, Taipei City 106319, TaiwanInstitute of Applied Mechanics, National Taiwan University, Taipei City 106319, TaiwanDepartment of Electrical Engineering, Graduate Institute of Photonics and Optoelectronics, National Taiwan University, Taipei City 106319, TaiwanDepartment of Mechanical Engineering, Advanced Institute of Manufacturing with High-Tech Innovations, National Chung Cheng University, Chiayi County 621301, TaiwanDepartment of Mechanical Engineering, Advanced Institute of Manufacturing with High-Tech Innovations, National Chung Cheng University, Chiayi County 621301, TaiwanInstitute of Applied Mechanics, National Taiwan University, Taipei City 106319, TaiwanNiFe<sub>2</sub>O<sub>4</sub> material is grown on carbon paper (CP) with the hydrothermal method for use as electrocatalysts in an alkaline electrolyzer. NiFe<sub>2</sub>O<sub>4</sub> material is used as the anode and cathode catalysts (named NiFe(+)/NiFe(−) hereafter). The results are compared with those obtained using CP/NiFe as the anode and CP/Ru as the cathode (named NiFe)(+)/Ru(−) hereafter). During cell operation with NiFe(+)/Ru(−), the current density reaches 500 mA/cm<sup>2</sup> at a cell voltage of 1.79 V, with a specific energy consumption of 4.9 kWh/m<sup>3</sup> and an energy efficiency of 66.2%. In comparison, for NiFe(+)/NiFe(−), the current density reaches 500 mA/cm<sup>2</sup> at a cell voltage of 2.23 V, with a specific energy consumption of 5.7 kWh/m<sup>3</sup> and an energy efficiency of 56.6%. The Faradaic efficiency is 96–99%. With the current density fixed at 400 mA/cm<sup>2</sup>, after performing a test for 150 h, the cell voltage with NiFe(+)/Ru(−) increases by 0.167 V, whereas that with NiFe(+)/NiFe(−) decreases by only 0.010 V. Good, long-term stability is demonstrated.https://www.mdpi.com/2072-666X/15/1/62alkaline water electrolysishydrothermal methodelectrocatalystNiFeRu
spellingShingle Ying-Chyi Wang
Shuo-En Yu
Yu-Lun Su
I-Chun Cheng
Yi-Cheng Chuang
Yong-Song Chen
Jian-Zhang Chen
NiFe<sub>2</sub>O<sub>4</sub> Material on Carbon Paper as an Electrocatalyst for Alkaline Water Electrolysis Module
Micromachines
alkaline water electrolysis
hydrothermal method
electrocatalyst
NiFe
Ru
title NiFe<sub>2</sub>O<sub>4</sub> Material on Carbon Paper as an Electrocatalyst for Alkaline Water Electrolysis Module
title_full NiFe<sub>2</sub>O<sub>4</sub> Material on Carbon Paper as an Electrocatalyst for Alkaline Water Electrolysis Module
title_fullStr NiFe<sub>2</sub>O<sub>4</sub> Material on Carbon Paper as an Electrocatalyst for Alkaline Water Electrolysis Module
title_full_unstemmed NiFe<sub>2</sub>O<sub>4</sub> Material on Carbon Paper as an Electrocatalyst for Alkaline Water Electrolysis Module
title_short NiFe<sub>2</sub>O<sub>4</sub> Material on Carbon Paper as an Electrocatalyst for Alkaline Water Electrolysis Module
title_sort nife sub 2 sub o sub 4 sub material on carbon paper as an electrocatalyst for alkaline water electrolysis module
topic alkaline water electrolysis
hydrothermal method
electrocatalyst
NiFe
Ru
url https://www.mdpi.com/2072-666X/15/1/62
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