Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate
In the title complex, [Cu(C5H5N2O2)(C14H18N3O)(H2O)]·1.33H2O, the CuII ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ide li...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809053768 |
| _version_ | 1828854443973541888 |
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| author | Ji-Chang Zhuang Fei-Long Hu Zhong-Jing Huang Yue Zhuang Feng Zhang |
| author_facet | Ji-Chang Zhuang Fei-Long Hu Zhong-Jing Huang Yue Zhuang Feng Zhang |
| author_sort | Ji-Chang Zhuang |
| collection | DOAJ |
| description | In the title complex, [Cu(C5H5N2O2)(C14H18N3O)(H2O)]·1.33H2O, the CuII ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxylate ligand. The apical position is occupied by a water molecule. In the crystal structure, O—H...O, O—H...N and N—H...O hydrogen bonds lead to a three-dimensional supramolecular network. |
| first_indexed | 2024-12-13T00:34:11Z |
| format | Article |
| id | doaj.art-28fcc284082d46e5aad15fd127a917fe |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:34:11Z |
| publishDate | 2010-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-28fcc284082d46e5aad15fd127a917fe2022-12-22T00:05:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m79m7910.1107/S1600536809053768Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrateJi-Chang ZhuangFei-Long HuZhong-Jing HuangYue ZhuangFeng ZhangIn the title complex, [Cu(C5H5N2O2)(C14H18N3O)(H2O)]·1.33H2O, the CuII ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxylate ligand. The apical position is occupied by a water molecule. In the crystal structure, O—H...O, O—H...N and N—H...O hydrogen bonds lead to a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536809053768 |
| spellingShingle | Ji-Chang Zhuang Fei-Long Hu Zhong-Jing Huang Yue Zhuang Feng Zhang Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate Acta Crystallographica Section E |
| title | Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate |
| title_full | Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate |
| title_fullStr | Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate |
| title_full_unstemmed | Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate |
| title_short | Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate |
| title_sort | aqua 2 5 ethyl 2 pyridyl amp 954 n 4 isopropyl 4 methyl 5 oxo 4 5 dihydroxyimidazol 1 ido amp 954 n1 5 methyl 1h pyrazole 3 carboxylato amp 954 2n2 o copper ii 1 33 hydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809053768 |
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