A D019 precipitate strengthened laser additively manufactured V and Nb bearing CoCrFeNi based high entropy alloys

Two novel HEA compositions of [Nb¯-(FeCoNi)12]Cr3 (Nb¯ = Nb, V) were designed using a high-entropy alloying strategy by analyzing traditional IN718 superalloy based on a cluster-plus-glue-atom model. And their thin-wall-shaped bulks were prepared by laser additive manufacturing, with an emphasis on...

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Main Authors: Jiawang Wu, Yaxiong Guo, Fangping Wang, Xiaojuan Shang, Jing Zhang, Qibin Liu
Format: Article
Language:English
Published: Elsevier 2023-11-01
Series:Materials & Design
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0264127523008791
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author Jiawang Wu
Yaxiong Guo
Fangping Wang
Xiaojuan Shang
Jing Zhang
Qibin Liu
author_facet Jiawang Wu
Yaxiong Guo
Fangping Wang
Xiaojuan Shang
Jing Zhang
Qibin Liu
author_sort Jiawang Wu
collection DOAJ
description Two novel HEA compositions of [Nb¯-(FeCoNi)12]Cr3 (Nb¯ = Nb, V) were designed using a high-entropy alloying strategy by analyzing traditional IN718 superalloy based on a cluster-plus-glue-atom model. And their thin-wall-shaped bulks were prepared by laser additive manufacturing, with an emphasis on the effects of using V atoms to substitute for Nb atoms on their microstructures and mechanical properties. Also, the strengthening mechanism induced by D019 precipitates of as-aged V2Nb4 HEA was discussed. After using V to substitute for Nb, the contents of inter-dendritic C14-Laves phases are effectively inhibited. The ductility is significantly improved with a small sacrifice of strength (i.e., σb ∼ 851 MPa and δ ∼ 16.8 % for V2Nb4 HEA). After aging treatment, the main microstructure transforms from fine dendrites to recrystallized equiaxed grains. The intercrossed needle-shaped D019 precipitates with a volume fraction of 7.2 % are uniformly distributed in the FCC matrix, which hinders the dislocation slip. Thereto, the as-96-hr-aged V2Nb4 HEA exhibits the most excellent strength-ductility trade-off (e.g., σs ∼ 721.5 MPa, σb ∼ 979.5 MPa with a sufficient δ of 7.5 %). The above findings provide references for the development of LAM high-performance HEAs originating from traditional alloys.
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spelling doaj.art-2907615e144547c9a004cda84c0ccdf02023-11-22T04:46:35ZengElsevierMaterials & Design0264-12752023-11-01235112464A D019 precipitate strengthened laser additively manufactured V and Nb bearing CoCrFeNi based high entropy alloysJiawang Wu0Yaxiong Guo1Fangping Wang2Xiaojuan Shang3Jing Zhang4Qibin Liu5Department of Metallurgical Engineering, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, PR China; Key Laboratory of Advanced Manufacturing Technology, Ministry of Education, Guizhou University, Guiyang 550025, PR ChinaDepartment of Metallurgical Engineering, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, PR China; Key Laboratory of Advanced Manufacturing Technology, Ministry of Education, Guizhou University, Guiyang 550025, PR China; Corresponding author at: Department of Metallurgical Engineering, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, PR China.Department of Metallurgical Engineering, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, PR China; Guiyang Vocational and Technical College, Guiyang 550081, PR ChinaDepartment of Metallurgical Engineering, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, PR China; Guizhou Jiaotong Technical College, Guiyang 5514005, PR ChinaDepartment of Metallurgical Engineering, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, PR ChinaDepartment of Metallurgical Engineering, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, PR China; Key Laboratory of Advanced Manufacturing Technology, Ministry of Education, Guizhou University, Guiyang 550025, PR ChinaTwo novel HEA compositions of [Nb¯-(FeCoNi)12]Cr3 (Nb¯ = Nb, V) were designed using a high-entropy alloying strategy by analyzing traditional IN718 superalloy based on a cluster-plus-glue-atom model. And their thin-wall-shaped bulks were prepared by laser additive manufacturing, with an emphasis on the effects of using V atoms to substitute for Nb atoms on their microstructures and mechanical properties. Also, the strengthening mechanism induced by D019 precipitates of as-aged V2Nb4 HEA was discussed. After using V to substitute for Nb, the contents of inter-dendritic C14-Laves phases are effectively inhibited. The ductility is significantly improved with a small sacrifice of strength (i.e., σb ∼ 851 MPa and δ ∼ 16.8 % for V2Nb4 HEA). After aging treatment, the main microstructure transforms from fine dendrites to recrystallized equiaxed grains. The intercrossed needle-shaped D019 precipitates with a volume fraction of 7.2 % are uniformly distributed in the FCC matrix, which hinders the dislocation slip. Thereto, the as-96-hr-aged V2Nb4 HEA exhibits the most excellent strength-ductility trade-off (e.g., σs ∼ 721.5 MPa, σb ∼ 979.5 MPa with a sufficient δ of 7.5 %). The above findings provide references for the development of LAM high-performance HEAs originating from traditional alloys.http://www.sciencedirect.com/science/article/pii/S0264127523008791High-entropy alloyingLaser additive manufacturingTensile propertiesD019 precipitates
spellingShingle Jiawang Wu
Yaxiong Guo
Fangping Wang
Xiaojuan Shang
Jing Zhang
Qibin Liu
A D019 precipitate strengthened laser additively manufactured V and Nb bearing CoCrFeNi based high entropy alloys
Materials & Design
High-entropy alloying
Laser additive manufacturing
Tensile properties
D019 precipitates
title A D019 precipitate strengthened laser additively manufactured V and Nb bearing CoCrFeNi based high entropy alloys
title_full A D019 precipitate strengthened laser additively manufactured V and Nb bearing CoCrFeNi based high entropy alloys
title_fullStr A D019 precipitate strengthened laser additively manufactured V and Nb bearing CoCrFeNi based high entropy alloys
title_full_unstemmed A D019 precipitate strengthened laser additively manufactured V and Nb bearing CoCrFeNi based high entropy alloys
title_short A D019 precipitate strengthened laser additively manufactured V and Nb bearing CoCrFeNi based high entropy alloys
title_sort d019 precipitate strengthened laser additively manufactured v and nb bearing cocrfeni based high entropy alloys
topic High-entropy alloying
Laser additive manufacturing
Tensile properties
D019 precipitates
url http://www.sciencedirect.com/science/article/pii/S0264127523008791
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