Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase Interface
Zeta potential is a surface characteristic formed on the solid surface and liquid interface. It is an interesting way to describe the surface properties of materials; thus, a series of four homemade polar embedded stationary phases that contain phosphate groups incorporated into hydrophobic ligands...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-01-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/3/968 |
| _version_ | 1797486012344041472 |
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| author | Mikołaj Dembek Szymon Bocian Bogusław Buszewski |
| author_facet | Mikołaj Dembek Szymon Bocian Bogusław Buszewski |
| author_sort | Mikołaj Dembek |
| collection | DOAJ |
| description | Zeta potential is a surface characteristic formed on the solid surface and liquid interface. It is an interesting way to describe the surface properties of materials; thus, a series of four homemade polar embedded stationary phases that contain phosphate groups incorporated into hydrophobic ligands were investigated according to surface zeta potential. Measurements were carried out using Zetasizer Nano ZS for the stationary phases suspensions prepared in various solvent and solvent binary mixtures. The negative zeta potential values were obtained for most cases due to negatively charged residual silanols and phosphate groups. However, in some solvents: tetrahydrofuran, isopropanol, and toluene zeta potential are positive. Additionally, it was observed that the zeta potential seems to be independent of the type of silica gel used for the stationary phase synthesis. |
| first_indexed | 2024-03-09T23:27:05Z |
| format | Article |
| id | doaj.art-290fed1ba4364777ba01a7aa11728fde |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T23:27:05Z |
| publishDate | 2022-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-290fed1ba4364777ba01a7aa11728fde2023-11-23T17:15:27ZengMDPI AGMolecules1420-30492022-01-0127396810.3390/molecules27030968Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase InterfaceMikołaj Dembek0Szymon Bocian1Bogusław Buszewski2Chair of Environmental Chemistry and Bioanalytics, Faculty of Chemistry, Nicolaus Copernicus University, 7 Gagarin St., 87-100 Toruń, PolandChair of Environmental Chemistry and Bioanalytics, Faculty of Chemistry, Nicolaus Copernicus University, 7 Gagarin St., 87-100 Toruń, PolandChair of Environmental Chemistry and Bioanalytics, Faculty of Chemistry, Nicolaus Copernicus University, 7 Gagarin St., 87-100 Toruń, PolandZeta potential is a surface characteristic formed on the solid surface and liquid interface. It is an interesting way to describe the surface properties of materials; thus, a series of four homemade polar embedded stationary phases that contain phosphate groups incorporated into hydrophobic ligands were investigated according to surface zeta potential. Measurements were carried out using Zetasizer Nano ZS for the stationary phases suspensions prepared in various solvent and solvent binary mixtures. The negative zeta potential values were obtained for most cases due to negatively charged residual silanols and phosphate groups. However, in some solvents: tetrahydrofuran, isopropanol, and toluene zeta potential are positive. Additionally, it was observed that the zeta potential seems to be independent of the type of silica gel used for the stationary phase synthesis.https://www.mdpi.com/1420-3049/27/3/968zeta potentialstationary phasesolventsurface |
| spellingShingle | Mikołaj Dembek Szymon Bocian Bogusław Buszewski Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase Interface Molecules zeta potential stationary phase solvent surface |
| title | Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase Interface |
| title_full | Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase Interface |
| title_fullStr | Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase Interface |
| title_full_unstemmed | Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase Interface |
| title_short | Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase Interface |
| title_sort | solvent influence on zeta potential of stationary phase mobile phase interface |
| topic | zeta potential stationary phase solvent surface |
| url | https://www.mdpi.com/1420-3049/27/3/968 |
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