4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate

In the cation of the title compound, C22H19N2+·NO3−, the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 2...

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Main Author: Li-Jing Cui
Format: Article
Language:English
Published: International Union of Crystallography 2009-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809018789
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author Li-Jing Cui
author_facet Li-Jing Cui
author_sort Li-Jing Cui
collection DOAJ
description In the cation of the title compound, C22H19N2+·NO3−, the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N—H...O and N—H...(O,O) hydrogen bonds link the molecules to form an infinite one-dimensional chain parallel to the c axis.
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spelling doaj.art-291252d08bd649dfabb9e02fbb31b3182022-12-21T17:23:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656o1361o136110.1107/S16005368090187894,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrateLi-Jing CuiIn the cation of the title compound, C22H19N2+·NO3−, the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N—H...O and N—H...(O,O) hydrogen bonds link the molecules to form an infinite one-dimensional chain parallel to the c axis.http://scripts.iucr.org/cgi-bin/paper?S1600536809018789
spellingShingle Li-Jing Cui
4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
Acta Crystallographica Section E
title 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_full 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_fullStr 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_full_unstemmed 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_short 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate
title_sort 4 5 diphenyl 2 p tolyl 1h imidazol 3 ium nitrate
url http://scripts.iucr.org/cgi-bin/paper?S1600536809018789
work_keys_str_mv AT lijingcui 45diphenyl2ptolyl1himidazol3iumnitrate