Solvent-Free Processed Cathode Slurry with Carbon Nanotube Conductors for Li-Ion Batteries

The increase in demand for energy storage devices, including portable electronic devices, electronic mobile devices, and energy storage systems, has led to substantial growth in the market for Li-ion batteries (LiB). However, the resulting environmental concerns from the waste of LiB and pollutants...

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Main Authors: Gyori Park, Hyun-Suk Kim, Kyung Jin Lee
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/2/324
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author Gyori Park
Hyun-Suk Kim
Kyung Jin Lee
author_facet Gyori Park
Hyun-Suk Kim
Kyung Jin Lee
author_sort Gyori Park
collection DOAJ
description The increase in demand for energy storage devices, including portable electronic devices, electronic mobile devices, and energy storage systems, has led to substantial growth in the market for Li-ion batteries (LiB). However, the resulting environmental concerns from the waste of LiB and pollutants from the manufacturing process have attracted considerable attention. In particular, N-methylpyrrolidone, which is utilized during the manufacturing process for preparing cathode or anode slurries, is a toxic organic pollutant. Therefore, the dry-based process for electrodes is of special interest nowadays. Herein, we report the fabrication of a cathode by a mortar-based dry process using NCM811, a carbon conductor, and poly(tetrafluoroethylene)binder. The electrochemical performance of the cathode was compared in terms of the types of conductors: carbon nanotubes and carbon black. The electrodes with carbon nanotubes showed an ameliorated performance in terms of cycle testing, capacity retention, and mechanical properties.
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spelling doaj.art-296e9e7b3a9b4763829548d4d08f04a12023-11-30T23:48:18ZengMDPI AGNanomaterials2079-49912023-01-0113232410.3390/nano13020324Solvent-Free Processed Cathode Slurry with Carbon Nanotube Conductors for Li-Ion BatteriesGyori Park0Hyun-Suk Kim1Kyung Jin Lee2Department of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 34134, Republic of KoreaDepartment of Materials Science and Engineering, Chungnam National University, Daejeon 34134, Republic of KoreaDepartment of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 34134, Republic of KoreaThe increase in demand for energy storage devices, including portable electronic devices, electronic mobile devices, and energy storage systems, has led to substantial growth in the market for Li-ion batteries (LiB). However, the resulting environmental concerns from the waste of LiB and pollutants from the manufacturing process have attracted considerable attention. In particular, N-methylpyrrolidone, which is utilized during the manufacturing process for preparing cathode or anode slurries, is a toxic organic pollutant. Therefore, the dry-based process for electrodes is of special interest nowadays. Herein, we report the fabrication of a cathode by a mortar-based dry process using NCM811, a carbon conductor, and poly(tetrafluoroethylene)binder. The electrochemical performance of the cathode was compared in terms of the types of conductors: carbon nanotubes and carbon black. The electrodes with carbon nanotubes showed an ameliorated performance in terms of cycle testing, capacity retention, and mechanical properties.https://www.mdpi.com/2079-4991/13/2/324Li ion batterydry processsolvent free electrodecarbon nanotubeNCM811
spellingShingle Gyori Park
Hyun-Suk Kim
Kyung Jin Lee
Solvent-Free Processed Cathode Slurry with Carbon Nanotube Conductors for Li-Ion Batteries
Nanomaterials
Li ion battery
dry process
solvent free electrode
carbon nanotube
NCM811
title Solvent-Free Processed Cathode Slurry with Carbon Nanotube Conductors for Li-Ion Batteries
title_full Solvent-Free Processed Cathode Slurry with Carbon Nanotube Conductors for Li-Ion Batteries
title_fullStr Solvent-Free Processed Cathode Slurry with Carbon Nanotube Conductors for Li-Ion Batteries
title_full_unstemmed Solvent-Free Processed Cathode Slurry with Carbon Nanotube Conductors for Li-Ion Batteries
title_short Solvent-Free Processed Cathode Slurry with Carbon Nanotube Conductors for Li-Ion Batteries
title_sort solvent free processed cathode slurry with carbon nanotube conductors for li ion batteries
topic Li ion battery
dry process
solvent free electrode
carbon nanotube
NCM811
url https://www.mdpi.com/2079-4991/13/2/324
work_keys_str_mv AT gyoripark solventfreeprocessedcathodeslurrywithcarbonnanotubeconductorsforliionbatteries
AT hyunsukkim solventfreeprocessedcathodeslurrywithcarbonnanotubeconductorsforliionbatteries
AT kyungjinlee solventfreeprocessedcathodeslurrywithcarbonnanotubeconductorsforliionbatteries