Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials

The preservation of cultural heritage monuments and artifacts requires the development of methods to produce water-repellent materials, which can offer protection against the effects of atmospheric water. Fluorosilanes are a very promising class of materials, as they act as precursors for the format...

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Main Authors: Fotios G. Adamopoulos, Evangelia C. Vouvoudi, Dimitris S. Achilias, Ioannis Karapanagiotis
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Heritage
Subjects:
Online Access:https://www.mdpi.com/2571-9408/4/4/150
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author Fotios G. Adamopoulos
Evangelia C. Vouvoudi
Dimitris S. Achilias
Ioannis Karapanagiotis
author_facet Fotios G. Adamopoulos
Evangelia C. Vouvoudi
Dimitris S. Achilias
Ioannis Karapanagiotis
author_sort Fotios G. Adamopoulos
collection DOAJ
description The preservation of cultural heritage monuments and artifacts requires the development of methods to produce water-repellent materials, which can offer protection against the effects of atmospheric water. Fluorosilanes are a very promising class of materials, as they act as precursors for the formation of low surface energy polymer networks. 1H,1H,2H,2H-perfluorooctyl-triethoxysilane is applied on marble, wood and the surfaces of other materials, such as glass, silicon wafer, brass, paper and silk. According to the measurements of static water contact angles, it is reported that superhydrophobicity and enhanced hydrophobicity are achieved on the surfaces of coated marble and wood, respectively. Hydrophobicity and hydrophilicity were observed on the treated surfaces of the other materials. More important, water repellency is achieved on any hydrophobic or superhydrophobic surface, as revealed by the very low sliding angles of water drops. The study is accompanied by colorimetric measurements to evaluate the effects of the treatment on the aesthetic appearances of the investigated materials. Finally, the capillary absorption test and a durability test are applied on treated wood and marble, respectively.
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spelling doaj.art-297c41d9521e4bcf85e0fe6f9383a1b82023-11-23T08:35:49ZengMDPI AGHeritage2571-94082021-09-01442668267510.3390/heritage4040150Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other MaterialsFotios G. Adamopoulos0Evangelia C. Vouvoudi1Dimitris S. Achilias2Ioannis Karapanagiotis3Laboratory of Polymers and Dyes Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-54124 Macedonia, GreeceLaboratory of Polymers and Dyes Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-54124 Macedonia, GreeceLaboratory of Polymers and Dyes Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-54124 Macedonia, GreeceDepartment of Management and Conservation of Ecclesiastical Cultural Heritage Objects, University Ecclesiastical Academy of Thessaloniki, GR-54250 Thessaloniki, GreeceThe preservation of cultural heritage monuments and artifacts requires the development of methods to produce water-repellent materials, which can offer protection against the effects of atmospheric water. Fluorosilanes are a very promising class of materials, as they act as precursors for the formation of low surface energy polymer networks. 1H,1H,2H,2H-perfluorooctyl-triethoxysilane is applied on marble, wood and the surfaces of other materials, such as glass, silicon wafer, brass, paper and silk. According to the measurements of static water contact angles, it is reported that superhydrophobicity and enhanced hydrophobicity are achieved on the surfaces of coated marble and wood, respectively. Hydrophobicity and hydrophilicity were observed on the treated surfaces of the other materials. More important, water repellency is achieved on any hydrophobic or superhydrophobic surface, as revealed by the very low sliding angles of water drops. The study is accompanied by colorimetric measurements to evaluate the effects of the treatment on the aesthetic appearances of the investigated materials. Finally, the capillary absorption test and a durability test are applied on treated wood and marble, respectively.https://www.mdpi.com/2571-9408/4/4/150hydrophobicsuperhydrophobicwater repellentfluorosilanecontact angle
spellingShingle Fotios G. Adamopoulos
Evangelia C. Vouvoudi
Dimitris S. Achilias
Ioannis Karapanagiotis
Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials
Heritage
hydrophobic
superhydrophobic
water repellent
fluorosilane
contact angle
title Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials
title_full Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials
title_fullStr Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials
title_full_unstemmed Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials
title_short Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials
title_sort fluorosilane water repellent coating for the protection of marble wood and other materials
topic hydrophobic
superhydrophobic
water repellent
fluorosilane
contact angle
url https://www.mdpi.com/2571-9408/4/4/150
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AT dimitrissachilias fluorosilanewaterrepellentcoatingfortheprotectionofmarblewoodandothermaterials
AT ioanniskarapanagiotis fluorosilanewaterrepellentcoatingfortheprotectionofmarblewoodandothermaterials