Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials
The preservation of cultural heritage monuments and artifacts requires the development of methods to produce water-repellent materials, which can offer protection against the effects of atmospheric water. Fluorosilanes are a very promising class of materials, as they act as precursors for the format...
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MDPI AG
2021-09-01
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Online Access: | https://www.mdpi.com/2571-9408/4/4/150 |
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author | Fotios G. Adamopoulos Evangelia C. Vouvoudi Dimitris S. Achilias Ioannis Karapanagiotis |
author_facet | Fotios G. Adamopoulos Evangelia C. Vouvoudi Dimitris S. Achilias Ioannis Karapanagiotis |
author_sort | Fotios G. Adamopoulos |
collection | DOAJ |
description | The preservation of cultural heritage monuments and artifacts requires the development of methods to produce water-repellent materials, which can offer protection against the effects of atmospheric water. Fluorosilanes are a very promising class of materials, as they act as precursors for the formation of low surface energy polymer networks. 1H,1H,2H,2H-perfluorooctyl-triethoxysilane is applied on marble, wood and the surfaces of other materials, such as glass, silicon wafer, brass, paper and silk. According to the measurements of static water contact angles, it is reported that superhydrophobicity and enhanced hydrophobicity are achieved on the surfaces of coated marble and wood, respectively. Hydrophobicity and hydrophilicity were observed on the treated surfaces of the other materials. More important, water repellency is achieved on any hydrophobic or superhydrophobic surface, as revealed by the very low sliding angles of water drops. The study is accompanied by colorimetric measurements to evaluate the effects of the treatment on the aesthetic appearances of the investigated materials. Finally, the capillary absorption test and a durability test are applied on treated wood and marble, respectively. |
first_indexed | 2024-03-10T04:00:12Z |
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id | doaj.art-297c41d9521e4bcf85e0fe6f9383a1b8 |
institution | Directory Open Access Journal |
issn | 2571-9408 |
language | English |
last_indexed | 2024-03-10T04:00:12Z |
publishDate | 2021-09-01 |
publisher | MDPI AG |
record_format | Article |
series | Heritage |
spelling | doaj.art-297c41d9521e4bcf85e0fe6f9383a1b82023-11-23T08:35:49ZengMDPI AGHeritage2571-94082021-09-01442668267510.3390/heritage4040150Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other MaterialsFotios G. Adamopoulos0Evangelia C. Vouvoudi1Dimitris S. Achilias2Ioannis Karapanagiotis3Laboratory of Polymers and Dyes Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-54124 Macedonia, GreeceLaboratory of Polymers and Dyes Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-54124 Macedonia, GreeceLaboratory of Polymers and Dyes Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-54124 Macedonia, GreeceDepartment of Management and Conservation of Ecclesiastical Cultural Heritage Objects, University Ecclesiastical Academy of Thessaloniki, GR-54250 Thessaloniki, GreeceThe preservation of cultural heritage monuments and artifacts requires the development of methods to produce water-repellent materials, which can offer protection against the effects of atmospheric water. Fluorosilanes are a very promising class of materials, as they act as precursors for the formation of low surface energy polymer networks. 1H,1H,2H,2H-perfluorooctyl-triethoxysilane is applied on marble, wood and the surfaces of other materials, such as glass, silicon wafer, brass, paper and silk. According to the measurements of static water contact angles, it is reported that superhydrophobicity and enhanced hydrophobicity are achieved on the surfaces of coated marble and wood, respectively. Hydrophobicity and hydrophilicity were observed on the treated surfaces of the other materials. More important, water repellency is achieved on any hydrophobic or superhydrophobic surface, as revealed by the very low sliding angles of water drops. The study is accompanied by colorimetric measurements to evaluate the effects of the treatment on the aesthetic appearances of the investigated materials. Finally, the capillary absorption test and a durability test are applied on treated wood and marble, respectively.https://www.mdpi.com/2571-9408/4/4/150hydrophobicsuperhydrophobicwater repellentfluorosilanecontact angle |
spellingShingle | Fotios G. Adamopoulos Evangelia C. Vouvoudi Dimitris S. Achilias Ioannis Karapanagiotis Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials Heritage hydrophobic superhydrophobic water repellent fluorosilane contact angle |
title | Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials |
title_full | Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials |
title_fullStr | Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials |
title_full_unstemmed | Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials |
title_short | Fluorosilane Water-Repellent Coating for the Protection of Marble, Wood and Other Materials |
title_sort | fluorosilane water repellent coating for the protection of marble wood and other materials |
topic | hydrophobic superhydrophobic water repellent fluorosilane contact angle |
url | https://www.mdpi.com/2571-9408/4/4/150 |
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