Densification of a NASICON-Type LATP Electrolyte Sheet by a Cold-Sintering Process
A NASICON-type Li<sub>1.3</sub>Al<sub>0.3</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> (LATP) electrolyte sheet for all-solid-state batteries was fabricated by a cold sintering process (CSP). The microstructure of the LATP sheet was co...
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MDPI AG
2021-08-01
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| Online Access: | https://www.mdpi.com/1996-1944/14/16/4737 |
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| author | Naoki Hamao Yuki Yamaguchi Koichi Hamamoto |
| author_facet | Naoki Hamao Yuki Yamaguchi Koichi Hamamoto |
| author_sort | Naoki Hamao |
| collection | DOAJ |
| description | A NASICON-type Li<sub>1.3</sub>Al<sub>0.3</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> (LATP) electrolyte sheet for all-solid-state batteries was fabricated by a cold sintering process (CSP). The microstructure of the LATP sheet was controlled to improve the wettability which is an essential factor in CSP. The porous sheets of LATP were prepared by calcination the green sheets to remove the organic components and form the porous structure. By the CSP using the porous sheets, the densification of grain boundary was observed and further densified with increasing reaction time. The total conductivity of the prepared LATP sheet was improved from 3.0 × 10<sup>−6</sup> S/cm to 3.0 × 10<sup>−4</sup> S/cm due to the formation of necks between the particles at the grain boundary. |
| first_indexed | 2024-03-10T08:37:50Z |
| format | Article |
| id | doaj.art-2984ae62f38d4ea6a59568b05875d80e |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-10T08:37:50Z |
| publishDate | 2021-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-2984ae62f38d4ea6a59568b05875d80e2023-11-22T08:32:08ZengMDPI AGMaterials1996-19442021-08-011416473710.3390/ma14164737Densification of a NASICON-Type LATP Electrolyte Sheet by a Cold-Sintering ProcessNaoki Hamao0Yuki Yamaguchi1Koichi Hamamoto2Innovative Functional Materials and Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98, Shimo-shidami Anagahora, Moriyama-ku, Nagoya 406-8560, JapanInnovative Functional Materials and Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98, Shimo-shidami Anagahora, Moriyama-ku, Nagoya 406-8560, JapanInnovative Functional Materials and Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98, Shimo-shidami Anagahora, Moriyama-ku, Nagoya 406-8560, JapanA NASICON-type Li<sub>1.3</sub>Al<sub>0.3</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> (LATP) electrolyte sheet for all-solid-state batteries was fabricated by a cold sintering process (CSP). The microstructure of the LATP sheet was controlled to improve the wettability which is an essential factor in CSP. The porous sheets of LATP were prepared by calcination the green sheets to remove the organic components and form the porous structure. By the CSP using the porous sheets, the densification of grain boundary was observed and further densified with increasing reaction time. The total conductivity of the prepared LATP sheet was improved from 3.0 × 10<sup>−6</sup> S/cm to 3.0 × 10<sup>−4</sup> S/cm due to the formation of necks between the particles at the grain boundary.https://www.mdpi.com/1996-1944/14/16/4737Li-ion conductorsolid electrolyteNASICON-type oxide |
| spellingShingle | Naoki Hamao Yuki Yamaguchi Koichi Hamamoto Densification of a NASICON-Type LATP Electrolyte Sheet by a Cold-Sintering Process Materials Li-ion conductor solid electrolyte NASICON-type oxide |
| title | Densification of a NASICON-Type LATP Electrolyte Sheet by a Cold-Sintering Process |
| title_full | Densification of a NASICON-Type LATP Electrolyte Sheet by a Cold-Sintering Process |
| title_fullStr | Densification of a NASICON-Type LATP Electrolyte Sheet by a Cold-Sintering Process |
| title_full_unstemmed | Densification of a NASICON-Type LATP Electrolyte Sheet by a Cold-Sintering Process |
| title_short | Densification of a NASICON-Type LATP Electrolyte Sheet by a Cold-Sintering Process |
| title_sort | densification of a nasicon type latp electrolyte sheet by a cold sintering process |
| topic | Li-ion conductor solid electrolyte NASICON-type oxide |
| url | https://www.mdpi.com/1996-1944/14/16/4737 |
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