Recent Advances in Asymmetric Catalytic Electrosynthesis
The renewed interest in electrosynthesis demonstrated by organic chemists in the last years has allowed for rapid development of new methodologies. In this review, advances in enantioselective electrosynthesis that rely on catalytic amounts of organic or metal-based chiral mediators are highlighted...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-09-01
|
| Series: | Catalysts |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4344/10/9/982 |
| _version_ | 1797554965994012672 |
|---|---|
| author | Cristiana Margarita Helena Lundberg |
| author_facet | Cristiana Margarita Helena Lundberg |
| author_sort | Cristiana Margarita |
| collection | DOAJ |
| description | The renewed interest in electrosynthesis demonstrated by organic chemists in the last years has allowed for rapid development of new methodologies. In this review, advances in enantioselective electrosynthesis that rely on catalytic amounts of organic or metal-based chiral mediators are highlighted with focus on the most recent developments up to July 2020. Examples of C-H functionalization, alkene functionalization, carboxylation and cross-electrophile couplings are discussed, along with their related mechanistic aspects. |
| first_indexed | 2024-03-10T16:39:31Z |
| format | Article |
| id | doaj.art-29878e9f961a417ca08862bd51671c96 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T16:39:31Z |
| publishDate | 2020-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-29878e9f961a417ca08862bd51671c962023-11-20T12:05:29ZengMDPI AGCatalysts2073-43442020-09-0110998210.3390/catal10090982Recent Advances in Asymmetric Catalytic ElectrosynthesisCristiana Margarita0Helena Lundberg1Department of Chemistry, KTH Royal Institute of Technology, SE-100 44 Stockholm, SwedenDepartment of Chemistry, KTH Royal Institute of Technology, SE-100 44 Stockholm, SwedenThe renewed interest in electrosynthesis demonstrated by organic chemists in the last years has allowed for rapid development of new methodologies. In this review, advances in enantioselective electrosynthesis that rely on catalytic amounts of organic or metal-based chiral mediators are highlighted with focus on the most recent developments up to July 2020. Examples of C-H functionalization, alkene functionalization, carboxylation and cross-electrophile couplings are discussed, along with their related mechanistic aspects.https://www.mdpi.com/2073-4344/10/9/982organic electrosynthesisasymmetric catalysiselectrochemistryenantioselectivityorganocatalysistransition-metal catalysis |
| spellingShingle | Cristiana Margarita Helena Lundberg Recent Advances in Asymmetric Catalytic Electrosynthesis Catalysts organic electrosynthesis asymmetric catalysis electrochemistry enantioselectivity organocatalysis transition-metal catalysis |
| title | Recent Advances in Asymmetric Catalytic Electrosynthesis |
| title_full | Recent Advances in Asymmetric Catalytic Electrosynthesis |
| title_fullStr | Recent Advances in Asymmetric Catalytic Electrosynthesis |
| title_full_unstemmed | Recent Advances in Asymmetric Catalytic Electrosynthesis |
| title_short | Recent Advances in Asymmetric Catalytic Electrosynthesis |
| title_sort | recent advances in asymmetric catalytic electrosynthesis |
| topic | organic electrosynthesis asymmetric catalysis electrochemistry enantioselectivity organocatalysis transition-metal catalysis |
| url | https://www.mdpi.com/2073-4344/10/9/982 |
| work_keys_str_mv | AT cristianamargarita recentadvancesinasymmetriccatalyticelectrosynthesis AT helenalundberg recentadvancesinasymmetriccatalyticelectrosynthesis |