Estimation of soil phosphorus availability via visible and near-infrared spectroscopy

ABSTRACT: Spectroscopic techniques have great potential to evaluate soil properties. However, there are still questions regarding the applicability of spectroscopy to analyze soil phosphorous (P) availability, especially in tropical soils with low nutrient contents. Therefore, this study evaluated t...

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Main Authors: Micael Felipe de Souza, Henrique Coutinho Junqueira Franco, Lucas Rios do Amaral
Format: Article
Language:English
Published: Universidade de São Paulo 2019-12-01
Series:Scientia Agricola
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-90162020000501601&tlng=en
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author Micael Felipe de Souza
Henrique Coutinho Junqueira Franco
Lucas Rios do Amaral
author_facet Micael Felipe de Souza
Henrique Coutinho Junqueira Franco
Lucas Rios do Amaral
author_sort Micael Felipe de Souza
collection DOAJ
description ABSTRACT: Spectroscopic techniques have great potential to evaluate soil properties. However, there are still questions regarding the applicability of spectroscopy to analyze soil phosphorous (P) availability, especially in tropical soils with low nutrient contents. Therefore, this study evaluated the possibility to estimate P availability in soil and its pools (labile, moderately labile and non-labile) via Vis-NIR spectroscopy based on intra-field calibration. We used soils from two different locations, a plot experiment that received application of phosphate fertilizers (Field-A) and a cultivated field where a grid soil sampling was performed (Field-B). We used the technique of diffuse reflectance in the visible and near-infrared (Vis-NIR) to obtain the spectra of soil samples. Predictive modeling for P availability and labile, moderately labile and non-labile pools of P in soil were obtained via partial least squares (PLS) regression; classification modeling was performed via Soft Independent Modeling of Class Analogy (SIMCA) on three P availability levels in order to overcome the limitation on quantifying P via Vis-NIR spectroscopy. We found that isolating P contents as the only variable (Field-A), Vis-NIR spectroscopy does not allow estimating P pools in the soil. In addition, quantification of P available in the soil via predictive modeling has limitations in tropical soils. On the other hand, estimating P content in soil through classes of availability is a feasible and promising alternative.
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spelling doaj.art-298f97812f504f48a708bb741f3b66482022-12-22T04:15:53ZengUniversidade de São PauloScientia Agricola1678-992X2019-12-0177510.1590/1678-992x-2018-0295Estimation of soil phosphorus availability via visible and near-infrared spectroscopyMicael Felipe de Souzahttps://orcid.org/0000-0002-9089-6749Henrique Coutinho Junqueira Francohttps://orcid.org/0000-0002-1218-7533Lucas Rios do Amaralhttps://orcid.org/0000-0001-8071-4449ABSTRACT: Spectroscopic techniques have great potential to evaluate soil properties. However, there are still questions regarding the applicability of spectroscopy to analyze soil phosphorous (P) availability, especially in tropical soils with low nutrient contents. Therefore, this study evaluated the possibility to estimate P availability in soil and its pools (labile, moderately labile and non-labile) via Vis-NIR spectroscopy based on intra-field calibration. We used soils from two different locations, a plot experiment that received application of phosphate fertilizers (Field-A) and a cultivated field where a grid soil sampling was performed (Field-B). We used the technique of diffuse reflectance in the visible and near-infrared (Vis-NIR) to obtain the spectra of soil samples. Predictive modeling for P availability and labile, moderately labile and non-labile pools of P in soil were obtained via partial least squares (PLS) regression; classification modeling was performed via Soft Independent Modeling of Class Analogy (SIMCA) on three P availability levels in order to overcome the limitation on quantifying P via Vis-NIR spectroscopy. We found that isolating P contents as the only variable (Field-A), Vis-NIR spectroscopy does not allow estimating P pools in the soil. In addition, quantification of P available in the soil via predictive modeling has limitations in tropical soils. On the other hand, estimating P content in soil through classes of availability is a feasible and promising alternative.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-90162020000501601&tlng=enpredictive modelingclassification modelprecision agriculturefractionation of phosphorussoil fertility
spellingShingle Micael Felipe de Souza
Henrique Coutinho Junqueira Franco
Lucas Rios do Amaral
Estimation of soil phosphorus availability via visible and near-infrared spectroscopy
Scientia Agricola
predictive modeling
classification model
precision agriculture
fractionation of phosphorus
soil fertility
title Estimation of soil phosphorus availability via visible and near-infrared spectroscopy
title_full Estimation of soil phosphorus availability via visible and near-infrared spectroscopy
title_fullStr Estimation of soil phosphorus availability via visible and near-infrared spectroscopy
title_full_unstemmed Estimation of soil phosphorus availability via visible and near-infrared spectroscopy
title_short Estimation of soil phosphorus availability via visible and near-infrared spectroscopy
title_sort estimation of soil phosphorus availability via visible and near infrared spectroscopy
topic predictive modeling
classification model
precision agriculture
fractionation of phosphorus
soil fertility
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-90162020000501601&tlng=en
work_keys_str_mv AT micaelfelipedesouza estimationofsoilphosphorusavailabilityviavisibleandnearinfraredspectroscopy
AT henriquecoutinhojunqueirafranco estimationofsoilphosphorusavailabilityviavisibleandnearinfraredspectroscopy
AT lucasriosdoamaral estimationofsoilphosphorusavailabilityviavisibleandnearinfraredspectroscopy