High Luminous Efficacy Phosphor-Converted Mass-Produced White LEDs Achieved by AlN Prebuffer and Transitional-Refraction-Index Patterned Sapphire Substrate

Constant advance in improving the luminous efficacy (<i>η</i><sub>L</sub>) of nitride-based light-emitting diodes (LEDs) plays a critical role for saving measurable amounts of energy. Further development is motivated to approach the efficiency limit for this material system w...

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Main Authors: Shuo Zhang, Meng Liang, Yan Yan, Jinpeng Huang, Yan Li, Tao Feng, Xueliang Zhu, Zhicong Li, Chenke Xu, Junxi Wang, Jinmin Li, Zhiqiang Liu, Xiaoyan Yi
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/12/10/1638
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author Shuo Zhang
Meng Liang
Yan Yan
Jinpeng Huang
Yan Li
Tao Feng
Xueliang Zhu
Zhicong Li
Chenke Xu
Junxi Wang
Jinmin Li
Zhiqiang Liu
Xiaoyan Yi
author_facet Shuo Zhang
Meng Liang
Yan Yan
Jinpeng Huang
Yan Li
Tao Feng
Xueliang Zhu
Zhicong Li
Chenke Xu
Junxi Wang
Jinmin Li
Zhiqiang Liu
Xiaoyan Yi
author_sort Shuo Zhang
collection DOAJ
description Constant advance in improving the luminous efficacy (<i>η</i><sub>L</sub>) of nitride-based light-emitting diodes (LEDs) plays a critical role for saving measurable amounts of energy. Further development is motivated to approach the efficiency limit for this material system while reducing the costs. In this work, strategies of using thin AlN prebuffer and transitional-refraction-index patterned sapphire substrate (TPSS) were proposed, which pushed up the efficiency of white LEDs (WLEDs). The AlN prebuffer was obtained through physical vapor deposition (PVD) method and TPSS was fabricated by dry-etched periodic silica arrays covered on sapphire. Devices in mass production confirmed that PVD AlN prebuffer was able to improve the light output power (<i>φ</i><sub>e</sub>) of blue LEDs (BLEDs) by 2.53% while increasing the productivity by ~8% through shortening the growth time. Additionally, BLEDs on TPSS exhibited an enhanced top <i>η</i><sub>ext</sub> of 5.65% in contrast to BLEDs on the conventional PSS through Monte Carlo ray-tracing simulation. Consequently, <i>φ</i><sub>e</sub> of BLEDs was experimentally enhanced by 10% at an injected current density (<i>J</i><sub>in</sub>) of 40 A/cm<sup>2</sup>. A peak <i>η</i><sub>L</sub> of 295.2 lm/W at a <i>J</i><sub>in</sub> of 0.9 A/cm<sup>2</sup> and the representative <i>η</i><sub>L</sub> of 282.4 lm/W at a <i>J</i><sub>in</sub> of 5.6 A/cm<sup>2</sup> for phosphor-converted WLEDs were achieved at a correlated color temperature of 4592 K.
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spelling doaj.art-29a7d2516e2c425cbe9e6bb5aba2eee92023-11-23T12:25:46ZengMDPI AGNanomaterials2079-49912022-05-011210163810.3390/nano12101638High Luminous Efficacy Phosphor-Converted Mass-Produced White LEDs Achieved by AlN Prebuffer and Transitional-Refraction-Index Patterned Sapphire SubstrateShuo Zhang0Meng Liang1Yan Yan2Jinpeng Huang3Yan Li4Tao Feng5Xueliang Zhu6Zhicong Li7Chenke Xu8Junxi Wang9Jinmin Li10Zhiqiang Liu11Xiaoyan Yi12Research and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaXiamen San’an Optoelectronic Technology Co., Ltd., Xiamen 361009, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaXiamen San’an Optoelectronic Technology Co., Ltd., Xiamen 361009, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaResearch and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, ChinaConstant advance in improving the luminous efficacy (<i>η</i><sub>L</sub>) of nitride-based light-emitting diodes (LEDs) plays a critical role for saving measurable amounts of energy. Further development is motivated to approach the efficiency limit for this material system while reducing the costs. In this work, strategies of using thin AlN prebuffer and transitional-refraction-index patterned sapphire substrate (TPSS) were proposed, which pushed up the efficiency of white LEDs (WLEDs). The AlN prebuffer was obtained through physical vapor deposition (PVD) method and TPSS was fabricated by dry-etched periodic silica arrays covered on sapphire. Devices in mass production confirmed that PVD AlN prebuffer was able to improve the light output power (<i>φ</i><sub>e</sub>) of blue LEDs (BLEDs) by 2.53% while increasing the productivity by ~8% through shortening the growth time. Additionally, BLEDs on TPSS exhibited an enhanced top <i>η</i><sub>ext</sub> of 5.65% in contrast to BLEDs on the conventional PSS through Monte Carlo ray-tracing simulation. Consequently, <i>φ</i><sub>e</sub> of BLEDs was experimentally enhanced by 10% at an injected current density (<i>J</i><sub>in</sub>) of 40 A/cm<sup>2</sup>. A peak <i>η</i><sub>L</sub> of 295.2 lm/W at a <i>J</i><sub>in</sub> of 0.9 A/cm<sup>2</sup> and the representative <i>η</i><sub>L</sub> of 282.4 lm/W at a <i>J</i><sub>in</sub> of 5.6 A/cm<sup>2</sup> for phosphor-converted WLEDs were achieved at a correlated color temperature of 4592 K.https://www.mdpi.com/2079-4991/12/10/1638light-emitting diodesAlN prebuffertransitional-refraction-index patterned sapphire substratelight output powerluminous efficacy
spellingShingle Shuo Zhang
Meng Liang
Yan Yan
Jinpeng Huang
Yan Li
Tao Feng
Xueliang Zhu
Zhicong Li
Chenke Xu
Junxi Wang
Jinmin Li
Zhiqiang Liu
Xiaoyan Yi
High Luminous Efficacy Phosphor-Converted Mass-Produced White LEDs Achieved by AlN Prebuffer and Transitional-Refraction-Index Patterned Sapphire Substrate
Nanomaterials
light-emitting diodes
AlN prebuffer
transitional-refraction-index patterned sapphire substrate
light output power
luminous efficacy
title High Luminous Efficacy Phosphor-Converted Mass-Produced White LEDs Achieved by AlN Prebuffer and Transitional-Refraction-Index Patterned Sapphire Substrate
title_full High Luminous Efficacy Phosphor-Converted Mass-Produced White LEDs Achieved by AlN Prebuffer and Transitional-Refraction-Index Patterned Sapphire Substrate
title_fullStr High Luminous Efficacy Phosphor-Converted Mass-Produced White LEDs Achieved by AlN Prebuffer and Transitional-Refraction-Index Patterned Sapphire Substrate
title_full_unstemmed High Luminous Efficacy Phosphor-Converted Mass-Produced White LEDs Achieved by AlN Prebuffer and Transitional-Refraction-Index Patterned Sapphire Substrate
title_short High Luminous Efficacy Phosphor-Converted Mass-Produced White LEDs Achieved by AlN Prebuffer and Transitional-Refraction-Index Patterned Sapphire Substrate
title_sort high luminous efficacy phosphor converted mass produced white leds achieved by aln prebuffer and transitional refraction index patterned sapphire substrate
topic light-emitting diodes
AlN prebuffer
transitional-refraction-index patterned sapphire substrate
light output power
luminous efficacy
url https://www.mdpi.com/2079-4991/12/10/1638
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