The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits

In this paper, we discuss the impact of the rank of coal, petrographic composition, and physico-chemical coal properties on the release and composition of syngas during coal gasification in a CO<sub>2</sub> atmosphere. This study used humic coals (parabituminous to anthracite) and lithot...

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Main Authors: Barbara Bielowicz, Jacek Misiak
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Resources
Subjects:
Online Access:https://www.mdpi.com/2079-9276/9/9/111
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author Barbara Bielowicz
Jacek Misiak
author_facet Barbara Bielowicz
Jacek Misiak
author_sort Barbara Bielowicz
collection DOAJ
description In this paper, we discuss the impact of the rank of coal, petrographic composition, and physico-chemical coal properties on the release and composition of syngas during coal gasification in a CO<sub>2</sub> atmosphere. This study used humic coals (parabituminous to anthracite) and lithotypes (bright coal and dull coal). Gasification was performed at temperatures between 600 and 1100 °C. It was found that the gas release depends on the temperature and rank of coal, and the reactivity increases with the increasing rank of coal. It was shown that the coal lithotype does not affect the gas composition or the process. Until 900 °C, the most intense processes were observed for higher rank coals. Above 1000 °C, the most reactive coals had a vitrinite reflectance of 0.5–0.6%. It was confirmed that the gasification of low-rank coal should be performed at temperatures above 1000 °C, and the reactivity of coal depends on the petrographic composition and physico-chemical features. It was shown that inertinite has a negative impact on the H<sub>2</sub> content; at 950 °C, the increase in H<sub>2</sub> depends on the rank of coal and vitrinite content. The physicochemical properties of coal rely on the content of maceral groups and the rank of coal. An improved understanding these relationships will allow the optimal selection of coal for gasification.
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spelling doaj.art-29a7f8e8b177403db1df8c09201fe0002023-11-20T13:03:34ZengMDPI AGResources2079-92762020-09-019911110.3390/resources9090111The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish DepositsBarbara Bielowicz0Jacek Misiak1Faculty of Geology, Geophysics and Environment Protection, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, PolandFaculty of Geology, Geophysics and Environment Protection, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, PolandIn this paper, we discuss the impact of the rank of coal, petrographic composition, and physico-chemical coal properties on the release and composition of syngas during coal gasification in a CO<sub>2</sub> atmosphere. This study used humic coals (parabituminous to anthracite) and lithotypes (bright coal and dull coal). Gasification was performed at temperatures between 600 and 1100 °C. It was found that the gas release depends on the temperature and rank of coal, and the reactivity increases with the increasing rank of coal. It was shown that the coal lithotype does not affect the gas composition or the process. Until 900 °C, the most intense processes were observed for higher rank coals. Above 1000 °C, the most reactive coals had a vitrinite reflectance of 0.5–0.6%. It was confirmed that the gasification of low-rank coal should be performed at temperatures above 1000 °C, and the reactivity of coal depends on the petrographic composition and physico-chemical features. It was shown that inertinite has a negative impact on the H<sub>2</sub> content; at 950 °C, the increase in H<sub>2</sub> depends on the rank of coal and vitrinite content. The physicochemical properties of coal rely on the content of maceral groups and the rank of coal. An improved understanding these relationships will allow the optimal selection of coal for gasification.https://www.mdpi.com/2079-9276/9/9/111coal gasificationreactivityrank of coalpetrographymaceral
spellingShingle Barbara Bielowicz
Jacek Misiak
The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits
Resources
coal gasification
reactivity
rank of coal
petrography
maceral
title The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits
title_full The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits
title_fullStr The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits
title_full_unstemmed The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits
title_short The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits
title_sort impact of coal s petrographic composition on its suitability for the gasification process the example of polish deposits
topic coal gasification
reactivity
rank of coal
petrography
maceral
url https://www.mdpi.com/2079-9276/9/9/111
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