Sr(NO3)(NH2SO3)·H2O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence
The approach of synergistically combining mixed chromophores has garnered significant attention attributed to its ability to leverage the advantages of both groups and design novel nonlinear optical (NLO) materials. Herein, Sr(NO3)(NH2SO3)·H2O, a noncentrosymmetric compound, which represents the fir...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2023-12-01
|
| Series: | Small Structures |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/sstr.202300274 |
| _version_ | 1797394663978565632 |
|---|---|
| author | Xuefei Wang Yang Li Zilong Chen Jihyun Lee Fangfang Zhang Kenneth R. Poeppelmeier Shilie Pan Kang Min Ok |
| author_facet | Xuefei Wang Yang Li Zilong Chen Jihyun Lee Fangfang Zhang Kenneth R. Poeppelmeier Shilie Pan Kang Min Ok |
| author_sort | Xuefei Wang |
| collection | DOAJ |
| description | The approach of synergistically combining mixed chromophores has garnered significant attention attributed to its ability to leverage the advantages of both groups and design novel nonlinear optical (NLO) materials. Herein, Sr(NO3)(NH2SO3)·H2O, a noncentrosymmetric compound, which represents the first reported nitrate sulfamate compound, is successfully designed and synthesized. The compound features zigzag [SrNO10(H2O)]∞ infinite layers, forming a honeycomb‐like graphene topology in its layered structure. The unique arrangement results in an excellent second harmonic generation response, 5.1 times that of KH2PO4, and an optimized birefringence of 0.06650 at 532 nm. In addition, the presence of interlayered covalent [NH2SO3] groups facilitates improved crystal growth habits, resulting in a large single crystal measuring 19.0 × 17.0 × 3.5 mm3. In this discovery, a new class of NLO materials is introduced and the scope of structural chemistry is significantly expanded. |
| first_indexed | 2024-03-09T00:23:03Z |
| format | Article |
| id | doaj.art-29b8c892b2f04a70917391e199cd31a6 |
| institution | Directory Open Access Journal |
| issn | 2688-4062 |
| language | English |
| last_indexed | 2024-03-09T00:23:03Z |
| publishDate | 2023-12-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Small Structures |
| spelling | doaj.art-29b8c892b2f04a70917391e199cd31a62023-12-12T05:17:30ZengWiley-VCHSmall Structures2688-40622023-12-01412n/an/a10.1002/sstr.202300274Sr(NO3)(NH2SO3)·H2O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized BirefringenceXuefei Wang0Yang Li1Zilong Chen2Jihyun Lee3Fangfang Zhang4Kenneth R. Poeppelmeier5Shilie Pan6Kang Min Ok7Department of Chemistry Sogang University Seoul 04107 Republic of KoreaDepartment of Chemistry Sogang University Seoul 04107 Republic of KoreaResearch Center for Crystal Materials CAS Key Laboratory of Functional Materials and Devices for Special Environments Xinjiang Technical Institute of Physics & Chemistry CAS Urumqi 830011 P. R. ChinaDepartment of Chemistry Sogang University Seoul 04107 Republic of KoreaResearch Center for Crystal Materials CAS Key Laboratory of Functional Materials and Devices for Special Environments Xinjiang Technical Institute of Physics & Chemistry CAS Urumqi 830011 P. R. ChinaDepartment of Chemistry Northwestern University Evanston IL 60208 USAResearch Center for Crystal Materials CAS Key Laboratory of Functional Materials and Devices for Special Environments Xinjiang Technical Institute of Physics & Chemistry CAS Urumqi 830011 P. R. ChinaDepartment of Chemistry Sogang University Seoul 04107 Republic of KoreaThe approach of synergistically combining mixed chromophores has garnered significant attention attributed to its ability to leverage the advantages of both groups and design novel nonlinear optical (NLO) materials. Herein, Sr(NO3)(NH2SO3)·H2O, a noncentrosymmetric compound, which represents the first reported nitrate sulfamate compound, is successfully designed and synthesized. The compound features zigzag [SrNO10(H2O)]∞ infinite layers, forming a honeycomb‐like graphene topology in its layered structure. The unique arrangement results in an excellent second harmonic generation response, 5.1 times that of KH2PO4, and an optimized birefringence of 0.06650 at 532 nm. In addition, the presence of interlayered covalent [NH2SO3] groups facilitates improved crystal growth habits, resulting in a large single crystal measuring 19.0 × 17.0 × 3.5 mm3. In this discovery, a new class of NLO materials is introduced and the scope of structural chemistry is significantly expanded.https://doi.org/10.1002/sstr.202300274birefringence measurementsnitrate sulfamatesnonlinear optical materialssecond harmonic generationultraviolet |
| spellingShingle | Xuefei Wang Yang Li Zilong Chen Jihyun Lee Fangfang Zhang Kenneth R. Poeppelmeier Shilie Pan Kang Min Ok Sr(NO3)(NH2SO3)·H2O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence Small Structures birefringence measurements nitrate sulfamates nonlinear optical materials second harmonic generation ultraviolet |
| title | Sr(NO3)(NH2SO3)·H2O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence |
| title_full | Sr(NO3)(NH2SO3)·H2O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence |
| title_fullStr | Sr(NO3)(NH2SO3)·H2O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence |
| title_full_unstemmed | Sr(NO3)(NH2SO3)·H2O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence |
| title_short | Sr(NO3)(NH2SO3)·H2O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence |
| title_sort | sr no3 nh2so3 ·h2o first nitrate sulfamate revealing remarkable second harmonic generation and optimized birefringence |
| topic | birefringence measurements nitrate sulfamates nonlinear optical materials second harmonic generation ultraviolet |
| url | https://doi.org/10.1002/sstr.202300274 |
| work_keys_str_mv | AT xuefeiwang srno3nh2so3h2ofirstnitratesulfamaterevealingremarkablesecondharmonicgenerationandoptimizedbirefringence AT yangli srno3nh2so3h2ofirstnitratesulfamaterevealingremarkablesecondharmonicgenerationandoptimizedbirefringence AT zilongchen srno3nh2so3h2ofirstnitratesulfamaterevealingremarkablesecondharmonicgenerationandoptimizedbirefringence AT jihyunlee srno3nh2so3h2ofirstnitratesulfamaterevealingremarkablesecondharmonicgenerationandoptimizedbirefringence AT fangfangzhang srno3nh2so3h2ofirstnitratesulfamaterevealingremarkablesecondharmonicgenerationandoptimizedbirefringence AT kennethrpoeppelmeier srno3nh2so3h2ofirstnitratesulfamaterevealingremarkablesecondharmonicgenerationandoptimizedbirefringence AT shiliepan srno3nh2so3h2ofirstnitratesulfamaterevealingremarkablesecondharmonicgenerationandoptimizedbirefringence AT kangminok srno3nh2so3h2ofirstnitratesulfamaterevealingremarkablesecondharmonicgenerationandoptimizedbirefringence |