Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base Ligands
This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions Mn(II) , Fe(II) , Co(II) and through the interaction with ligand (decyl xanthate potassium) and complexes of formula [M(DEXANT)2] were formed , as : M= Mn(...
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| Format: | Article |
| Language: | Arabic |
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College of Education for Pure Sciences
2023-09-01
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| Series: | مجلة التربية والعلم |
| Subjects: | |
| Online Access: | https://edusj.mosuljournals.com/article_178436_4f695fd123d5821d41c47b3a1ffd9b9e.pdf |
| _version_ | 1797728950698377216 |
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| author | Mahameed Ameen Al-Badrane Fadia J Ahmed |
| author_facet | Mahameed Ameen Al-Badrane Fadia J Ahmed |
| author_sort | Mahameed Ameen Al-Badrane |
| collection | DOAJ |
| description | This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions Mn(II) , Fe(II) , Co(II) and through the interaction with ligand (decyl xanthate potassium) and complexes of formula [M(DEXANT)2] were formed , as : M= Mn(II) , Fe(II) , Co(II) and then the interaction of these complexes with Lewis bivalve bases , to give complexes with the formula [M(DEXANT)2 . L], where : L= 1,10-phenanthroline , 8-hydroxyquinoline, 2,2-Pipyridine. The prepared complexes were characterized by melting point , atomic absorption, micro elemental analysis , infrared , nuclear magnetic resonance spectrum of the proton , molar electrical conductivity , electronic absorption spectra and susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type [M(DEXANT)2] had a tetrahedral geometry, while complexes of type [M(DEXANT)2.L] had an octahedral geometry,The conductivity measurements proved the non-electrolytic behavior of all compounds . |
| first_indexed | 2024-03-12T11:21:44Z |
| format | Article |
| id | doaj.art-29bbf1cde6f449d2b56d676303f16736 |
| institution | Directory Open Access Journal |
| issn | 1812-125X 2664-2530 |
| language | Arabic |
| last_indexed | 2024-03-12T11:21:44Z |
| publishDate | 2023-09-01 |
| publisher | College of Education for Pure Sciences |
| record_format | Article |
| series | مجلة التربية والعلم |
| spelling | doaj.art-29bbf1cde6f449d2b56d676303f167362023-09-01T18:04:20ZaraCollege of Education for Pure Sciencesمجلة التربية والعلم1812-125X2664-25302023-09-01323475910.33899/edusj.2023.139116.1349178436Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base LigandsMahameed Ameen Al-Badrane0Fadia J Ahmed1Dept.Chemistry,Education Collegefor Pure Science, University of MosulDepartment of Chemistry, college of education for pure scienceThis research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions Mn(II) , Fe(II) , Co(II) and through the interaction with ligand (decyl xanthate potassium) and complexes of formula [M(DEXANT)2] were formed , as : M= Mn(II) , Fe(II) , Co(II) and then the interaction of these complexes with Lewis bivalve bases , to give complexes with the formula [M(DEXANT)2 . L], where : L= 1,10-phenanthroline , 8-hydroxyquinoline, 2,2-Pipyridine. The prepared complexes were characterized by melting point , atomic absorption, micro elemental analysis , infrared , nuclear magnetic resonance spectrum of the proton , molar electrical conductivity , electronic absorption spectra and susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type [M(DEXANT)2] had a tetrahedral geometry, while complexes of type [M(DEXANT)2.L] had an octahedral geometry,The conductivity measurements proved the non-electrolytic behavior of all compounds .https://edusj.mosuljournals.com/article_178436_4f695fd123d5821d41c47b3a1ffd9b9e.pdfxanthate,,,،؛manganese(ii),,,،؛iron(ii),,,،؛cobalt(ii),,,،؛complexes |
| spellingShingle | Mahameed Ameen Al-Badrane Fadia J Ahmed Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base Ligands مجلة التربية والعلم xanthate,, ,،؛manganese(ii),, ,،؛iron(ii),, ,،؛cobalt(ii),, ,،؛complexes |
| title | Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base Ligands |
| title_full | Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base Ligands |
| title_fullStr | Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base Ligands |
| title_full_unstemmed | Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base Ligands |
| title_short | Synthesis and Characterization of Some Complexes of Manganese(II), Iron(II) and Cobalt(II) With Decylxanthate and Their Adducts With Nitrogen Base Ligands |
| title_sort | synthesis and characterization of some complexes of manganese ii iron ii and cobalt ii with decylxanthate and their adducts with nitrogen base ligands |
| topic | xanthate,, ,،؛manganese(ii),, ,،؛iron(ii),, ,،؛cobalt(ii),, ,،؛complexes |
| url | https://edusj.mosuljournals.com/article_178436_4f695fd123d5821d41c47b3a1ffd9b9e.pdf |
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