Effect of Modification with a Biocide Containing Metal Nanoparticles on Selected LDPE Properties

In this work, the physicomechanical, chemical and thermal properties of low-density polyethylene (LDPE) modified with a biocide containing metal nanoparticles: nanoAg, nanoCu, and nanoFe<sub>2</sub>O<sub>3</sub> were examined. The presented studies, apart from the previously...

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Main Authors: Katarzyna Janczak, Daria Lisewska, Alicja Mazuryk, Rafał Malinowski
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Journal of Composites Science
Subjects:
Online Access:https://www.mdpi.com/2504-477X/7/1/13
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author Katarzyna Janczak
Daria Lisewska
Alicja Mazuryk
Rafał Malinowski
author_facet Katarzyna Janczak
Daria Lisewska
Alicja Mazuryk
Rafał Malinowski
author_sort Katarzyna Janczak
collection DOAJ
description In this work, the physicomechanical, chemical and thermal properties of low-density polyethylene (LDPE) modified with a biocide containing metal nanoparticles: nanoAg, nanoCu, and nanoFe<sub>2</sub>O<sub>3</sub> were examined. The presented studies, apart from the previously proven antimicrobial effectiveness, have shown that the application of the biocide in concentrations of 0.5% and 1% has the least influence on the remaining properties. In the remaining concentrations (2–5%), despite the lack of significant influence on the chemical structure, the biocide primarily influenced the strength properties and melt flow rate (MFR). Previous research showed almost 100% antimicrobiological properties against bacteria and fungi of samples with the addition of 4% biocide. For such samples, the presented studies showed a decrease in MFR by approx. 17%, tensile strength at break by approx. 45%, an increase in elongation at breaking by approx. 25%, a decrease in density >2%, no increase in water absorption, and no significant changes in the chemical structure and in thermal properties in relation to LDPE without biocide.
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spelling doaj.art-29c4d7cfb950429eb2a0e30119fe08622023-11-30T22:54:15ZengMDPI AGJournal of Composites Science2504-477X2023-01-01711310.3390/jcs7010013Effect of Modification with a Biocide Containing Metal Nanoparticles on Selected LDPE PropertiesKatarzyna Janczak0Daria Lisewska1Alicja Mazuryk2Rafał Malinowski3Łukasiewicz Research Network—Institute for Engineering of Polymer Materials and Dyes, Marii Skłodowskiej-Curie 55, 87-100 Torun, PolandŁukasiewicz Research Network—Institute for Engineering of Polymer Materials and Dyes, Marii Skłodowskiej-Curie 55, 87-100 Torun, PolandŁukasiewicz Research Network—Institute for Engineering of Polymer Materials and Dyes, Marii Skłodowskiej-Curie 55, 87-100 Torun, PolandŁukasiewicz Research Network—Institute for Engineering of Polymer Materials and Dyes, Marii Skłodowskiej-Curie 55, 87-100 Torun, PolandIn this work, the physicomechanical, chemical and thermal properties of low-density polyethylene (LDPE) modified with a biocide containing metal nanoparticles: nanoAg, nanoCu, and nanoFe<sub>2</sub>O<sub>3</sub> were examined. The presented studies, apart from the previously proven antimicrobial effectiveness, have shown that the application of the biocide in concentrations of 0.5% and 1% has the least influence on the remaining properties. In the remaining concentrations (2–5%), despite the lack of significant influence on the chemical structure, the biocide primarily influenced the strength properties and melt flow rate (MFR). Previous research showed almost 100% antimicrobiological properties against bacteria and fungi of samples with the addition of 4% biocide. For such samples, the presented studies showed a decrease in MFR by approx. 17%, tensile strength at break by approx. 45%, an increase in elongation at breaking by approx. 25%, a decrease in density >2%, no increase in water absorption, and no significant changes in the chemical structure and in thermal properties in relation to LDPE without biocide.https://www.mdpi.com/2504-477X/7/1/13polyethylenenanoparticlesMFRphysical and mechanical propertiesDSCFTIR
spellingShingle Katarzyna Janczak
Daria Lisewska
Alicja Mazuryk
Rafał Malinowski
Effect of Modification with a Biocide Containing Metal Nanoparticles on Selected LDPE Properties
Journal of Composites Science
polyethylene
nanoparticles
MFR
physical and mechanical properties
DSC
FTIR
title Effect of Modification with a Biocide Containing Metal Nanoparticles on Selected LDPE Properties
title_full Effect of Modification with a Biocide Containing Metal Nanoparticles on Selected LDPE Properties
title_fullStr Effect of Modification with a Biocide Containing Metal Nanoparticles on Selected LDPE Properties
title_full_unstemmed Effect of Modification with a Biocide Containing Metal Nanoparticles on Selected LDPE Properties
title_short Effect of Modification with a Biocide Containing Metal Nanoparticles on Selected LDPE Properties
title_sort effect of modification with a biocide containing metal nanoparticles on selected ldpe properties
topic polyethylene
nanoparticles
MFR
physical and mechanical properties
DSC
FTIR
url https://www.mdpi.com/2504-477X/7/1/13
work_keys_str_mv AT katarzynajanczak effectofmodificationwithabiocidecontainingmetalnanoparticlesonselectedldpeproperties
AT darialisewska effectofmodificationwithabiocidecontainingmetalnanoparticlesonselectedldpeproperties
AT alicjamazuryk effectofmodificationwithabiocidecontainingmetalnanoparticlesonselectedldpeproperties
AT rafałmalinowski effectofmodificationwithabiocidecontainingmetalnanoparticlesonselectedldpeproperties