catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate]
In the title coordination polymer, {[Ag(C12H20N2O2)]ClO4·0.5H2O}n, the AgI cation is coordinated by two N atoms from two 1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)&...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812016406 |
| _version_ | 1819278166794960896 |
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| author | Ay Jong Chun-Wei Yeh Fu-Chang Huang Shui-Chuan Lin Maw-Cherng Suen |
| author_facet | Ay Jong Chun-Wei Yeh Fu-Chang Huang Shui-Chuan Lin Maw-Cherng Suen |
| author_sort | Ay Jong |
| collection | DOAJ |
| description | In the title coordination polymer, {[Ag(C12H20N2O2)]ClO4·0.5H2O}n, the AgI cation is coordinated by two N atoms from two 1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag+ cations, forming a polymeric chain running along the c axis. The lattice water molecule is situated on a twofold rotation axis, and links to the perchlorate anion via an O—H...O hydrogen bond. The long Ag...O separation of 3.200 (4) Å indicates a weak interaction between the perchlorate anion and the AgI cation. Weak C—H...O hydrogen bonding occurs between the chain and the lattice water molecule and between the chain and perchlorate anions. Both five-membered rings of the L ligand display envelope conformations; in one five-membered ring, the flap C atom is disordered on opposite sides of the ring with occupancies of 0.65 and 0.35. |
| first_indexed | 2024-12-24T00:07:42Z |
| format | Article |
| id | doaj.art-29dadcb513ab417a99e2d3714200f0d4 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:07:42Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-29dadcb513ab417a99e2d3714200f0d42022-12-21T17:24:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m637m63810.1107/S1600536812016406catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate]Ay JongChun-Wei YehFu-Chang HuangShui-Chuan LinMaw-Cherng SuenIn the title coordination polymer, {[Ag(C12H20N2O2)]ClO4·0.5H2O}n, the AgI cation is coordinated by two N atoms from two 1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag+ cations, forming a polymeric chain running along the c axis. The lattice water molecule is situated on a twofold rotation axis, and links to the perchlorate anion via an O—H...O hydrogen bond. The long Ag...O separation of 3.200 (4) Å indicates a weak interaction between the perchlorate anion and the AgI cation. Weak C—H...O hydrogen bonding occurs between the chain and the lattice water molecule and between the chain and perchlorate anions. Both five-membered rings of the L ligand display envelope conformations; in one five-membered ring, the flap C atom is disordered on opposite sides of the ring with occupancies of 0.65 and 0.35.http://scripts.iucr.org/cgi-bin/paper?S1600536812016406 |
| spellingShingle | Ay Jong Chun-Wei Yeh Fu-Chang Huang Shui-Chuan Lin Maw-Cherng Suen catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate] Acta Crystallographica Section E |
| title | catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate] |
| title_full | catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate] |
| title_fullStr | catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate] |
| title_full_unstemmed | catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate] |
| title_short | catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate] |
| title_sort | catena poly silver i amp 956 1 2 bis 4 4 dimethyl 4 5 dihydro 1 3 oxazol 2 yl ethane amp 954 2n n amp 8242 perchlorate hemihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812016406 |
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