Crystal structure of (E)-N1-[(anthracen-9-yl)methylidene]-N4-phenylbenzene-1,4-diamine
The title compound, C27H20N2, a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenylenediamine, crystallizes with three independent molecules in the asymmetric unit. The three molecules have slightly varying overall conformations, all having tra...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016020612 |
| _version_ | 1818322026673209344 |
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| author | Md. Serajul Haque Faizi Ashanul Haque Musheer Ahmad Irina A. Golenya |
| author_facet | Md. Serajul Haque Faizi Ashanul Haque Musheer Ahmad Irina A. Golenya |
| author_sort | Md. Serajul Haque Faizi |
| collection | DOAJ |
| description | The title compound, C27H20N2, a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenylenediamine, crystallizes with three independent molecules in the asymmetric unit. The three molecules have slightly varying overall conformations, all having trans conformations with respect to the C=N bond. In the crystal, the packing features N—H...N hydrogen bonds, which connect molecules into chains extending along the c-axis direction, interlinked by C—H...π interactions (minimum H...Cg = 2.65 Å) into sheets lying parallel to (001). |
| first_indexed | 2024-12-13T10:50:15Z |
| format | Article |
| id | doaj.art-29e0fd35da1d4f899aa6f582a4b6f2b2 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-13T10:50:15Z |
| publishDate | 2017-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-29e0fd35da1d4f899aa6f582a4b6f2b22022-12-21T23:49:53ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-02-0173213714010.1107/S2056989016020612zs2373Crystal structure of (E)-N1-[(anthracen-9-yl)methylidene]-N4-phenylbenzene-1,4-diamineMd. Serajul Haque Faizi0Ashanul Haque1Musheer Ahmad2Irina A. Golenya3Department of Chemistry, College of Science, Sultan Qaboos University, PO Box 36 Al-Khod 123, Muscat, Sultanate of OmanDepartment of Chemistry, College of Science, Sultan Qaboos University, PO Box 36 Al-Khod 123, Muscat, Sultanate of OmanDepartment of Applied Chemistry, Aligarh Muslim University 202 002 UP , IndiaNational Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv, UkraineThe title compound, C27H20N2, a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenylenediamine, crystallizes with three independent molecules in the asymmetric unit. The three molecules have slightly varying overall conformations, all having trans conformations with respect to the C=N bond. In the crystal, the packing features N—H...N hydrogen bonds, which connect molecules into chains extending along the c-axis direction, interlinked by C—H...π interactions (minimum H...Cg = 2.65 Å) into sheets lying parallel to (001).http://scripts.iucr.org/cgi-bin/paper?S2056989016020612crystal structurehydrogen bondingSchiff baseC—H...π interactions9-anthraldehydeN-phenyl-p-phenylenediamineAMPDanthracene |
| spellingShingle | Md. Serajul Haque Faizi Ashanul Haque Musheer Ahmad Irina A. Golenya Crystal structure of (E)-N1-[(anthracen-9-yl)methylidene]-N4-phenylbenzene-1,4-diamine Acta Crystallographica Section E: Crystallographic Communications crystal structure hydrogen bonding Schiff base C—H...π interactions 9-anthraldehyde N-phenyl-p-phenylenediamine AMPD anthracene |
| title | Crystal structure of (E)-N1-[(anthracen-9-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_full | Crystal structure of (E)-N1-[(anthracen-9-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_fullStr | Crystal structure of (E)-N1-[(anthracen-9-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_full_unstemmed | Crystal structure of (E)-N1-[(anthracen-9-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_short | Crystal structure of (E)-N1-[(anthracen-9-yl)methylidene]-N4-phenylbenzene-1,4-diamine |
| title_sort | crystal structure of e n1 anthracen 9 yl methylidene n4 phenylbenzene 1 4 diamine |
| topic | crystal structure hydrogen bonding Schiff base C—H...π interactions 9-anthraldehyde N-phenyl-p-phenylenediamine AMPD anthracene |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016020612 |
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