Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck Reaction
In this paper we report examples of the Heck reaction in the new moisture stable ambient temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6). We have found that the yield of product is comparable with Heck reactions carried out in DMF, the conventional solvent for th...
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| Format: | Article |
| Language: | English |
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MDPI AG
2000-06-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/5/6/851/ |
| _version_ | 1818217200091136000 |
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| author | Andrea Dallas Joshua Howarth |
| author_facet | Andrea Dallas Joshua Howarth |
| author_sort | Andrea Dallas |
| collection | DOAJ |
| description | In this paper we report examples of the Heck reaction in the new moisture stable ambient temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6). We have found that the yield of product is comparable with Heck reactions carried out in DMF, the conventional solvent for this reaction, and that the ionic liquid/catalyst mixture can be recycled several times. |
| first_indexed | 2024-12-12T07:04:05Z |
| format | Article |
| id | doaj.art-2a0cc305a38b4f17b6b559a601f30135 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-12T07:04:05Z |
| publishDate | 2000-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-2a0cc305a38b4f17b6b559a601f301352022-12-22T00:33:47ZengMDPI AGMolecules1420-30492000-06-015685185510.3390/50600851Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck ReactionAndrea DallasJoshua HowarthIn this paper we report examples of the Heck reaction in the new moisture stable ambient temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6). We have found that the yield of product is comparable with Heck reactions carried out in DMF, the conventional solvent for this reaction, and that the ionic liquid/catalyst mixture can be recycled several times.http://www.mdpi.com/1420-3049/5/6/851/Ionic liquidsHeck rection[bmim]PF6[bmim]BF4 |
| spellingShingle | Andrea Dallas Joshua Howarth Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck Reaction Molecules Ionic liquids Heck rection [bmim]PF6 [bmim]BF4 |
| title | Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck Reaction |
| title_full | Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck Reaction |
| title_fullStr | Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck Reaction |
| title_full_unstemmed | Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck Reaction |
| title_short | Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck Reaction |
| title_sort | moisture stable ambient temperature ionic liquids solvents for the new millennium 1 the heck reaction |
| topic | Ionic liquids Heck rection [bmim]PF6 [bmim]BF4 |
| url | http://www.mdpi.com/1420-3049/5/6/851/ |
| work_keys_str_mv | AT andreadallas moisturestableambienttemperatureionicliquidssolventsforthenewmillennium1theheckreaction AT joshuahowarth moisturestableambienttemperatureionicliquidssolventsforthenewmillennium1theheckreaction |