Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization
Light-induced [2 + 2] cycloaddition is the most efficient way to generate cyclobutanes, while suffering from limitations of specific selectivity. Here the authors report a cage-confined photocatalytic [2 + 2] cycloaddition to enable the unusual production of syn-head-to-head cyclobutane derivatives...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2020-09-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-020-18487-5 |
| _version_ | 1818750824605548544 |
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| author | Jing-Si Wang Kai Wu Changzhen Yin Kang Li Yahao Huang Jia Ruan Ximin Feng Peng Hu Cheng-Yong Su |
| author_facet | Jing-Si Wang Kai Wu Changzhen Yin Kang Li Yahao Huang Jia Ruan Ximin Feng Peng Hu Cheng-Yong Su |
| author_sort | Jing-Si Wang |
| collection | DOAJ |
| description | Light-induced [2 + 2] cycloaddition is the most efficient way to generate cyclobutanes, while suffering from limitations of specific selectivity. Here the authors report a cage-confined photocatalytic [2 + 2] cycloaddition to enable the unusual production of syn-head-to-head cyclobutane derivatives selectively. |
| first_indexed | 2024-12-18T04:25:49Z |
| format | Article |
| id | doaj.art-2a38bdfb6400470382103cd7323e4348 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-18T04:25:49Z |
| publishDate | 2020-09-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-2a38bdfb6400470382103cd7323e43482022-12-21T21:21:06ZengNature PortfolioNature Communications2041-17232020-09-011111910.1038/s41467-020-18487-5Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitizationJing-Si Wang0Kai Wu1Changzhen Yin2Kang Li3Yahao Huang4Jia Ruan5Ximin Feng6Peng Hu7Cheng-Yong Su8MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityLight-induced [2 + 2] cycloaddition is the most efficient way to generate cyclobutanes, while suffering from limitations of specific selectivity. Here the authors report a cage-confined photocatalytic [2 + 2] cycloaddition to enable the unusual production of syn-head-to-head cyclobutane derivatives selectively.https://doi.org/10.1038/s41467-020-18487-5 |
| spellingShingle | Jing-Si Wang Kai Wu Changzhen Yin Kang Li Yahao Huang Jia Ruan Ximin Feng Peng Hu Cheng-Yong Su Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization Nature Communications |
| title | Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization |
| title_full | Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization |
| title_fullStr | Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization |
| title_full_unstemmed | Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization |
| title_short | Cage-confined photocatalysis for wide-scope unusually selective [2 + 2] cycloaddition through visible-light triplet sensitization |
| title_sort | cage confined photocatalysis for wide scope unusually selective 2 2 cycloaddition through visible light triplet sensitization |
| url | https://doi.org/10.1038/s41467-020-18487-5 |
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