Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate

Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-trichlorophenyl)cyclohex-3-ene-1-carboxylate

The title compound, C19H17Cl3N2O3, has been prepared in a cyclocondensation reaction between 2,3,5-trichlorobenzaldehye and 4-acetyl-2-methyl-1H-imidazole. The cyclohexenone ring adopts an envelope conformation with the C atom substituted by the trichlorophenyl ring as the flap. The mutually trans e...

Full description

Bibliographic Details
Main Authors:	Billava J. Mohan, Balladka K. Sarojini, Hemmige S. Yathirajan, Ravindranath Rathore, Christopher Glidewell
Format:	Article
Language:	English
Published:	International Union of Crystallography 2016-01-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure cyclocondensation reaction molecular stereochemistry molecular conformation hydrogen bonding
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989015023245

Similar Items

1,1′-{1,4-Phenylene bis[3-(6-chloro-2-methyl-4-phenylquinolin-3-yl)-4,5-dihydro-1H-pyrazole-5,1-diyl]}dibutan-1-one
by: Allaoua Kedjadja, et al.
Published: (2015-10-01)

Ethyl 6-(6-methoxy-2-naphthyl)-2-oxo-4-(2-thienyl)cyclohex-3-ene-1-carboxylate
by: Hongqi Li, et al.
Published: (2009-07-01)

1-[3-(2-Methyl-4-phenylquinolin-3-yl)-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl]-propane-1-one
by: Allaoua Kedjadja, et al.
Published: (2015-06-01)

Crystal structures of two C,N-disubstituted acetamides: 2-(4-chlorophenyl)-N-(2-iodophenyl)acetamide and 2-(4-chlorophenyl)-N-(pyrazin-2-yl)acetamide
by: Badiadka Narayana, et al.
Published: (2016-09-01)

The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one
by: Marisiddaiah Girisha, et al.
Published: (2016-08-01)

Syntheses and crystal structures of 4-(4-nitrophenyl)piperazin-1-ium benzoate monohydrate and 4-(4-nitrophenyl)piperazin-1-ium 2-carboxy-4,6-dinitrophenolate
by: Holehundi J. Shankara Prasad, et al.
Published: (2022-08-01)

Crystal structures of (E)-1-{3-[(5-fluoro-2-hydroxybenzylidene)amino]phenyl}ethanone and of a fourth polymorph of (E)-1-{3-[(2-hydroxy-3-methoxybenzylidene)amino]phenyl}ethanone
by: Marisiddaiah Girisha, et al.
Published: (2017-12-01)

Bis-(1-phenyl-5-nitro-6-methylthio-1,2,3,4-tetrahydropyrimidinyl)benzene and Bis-(1-phenyl-5-nitro-6-methylthio-1,2,3,4-tetrahydropyrimidinyl)diphenyl
by: J.N. Vishwakarma, et al.
Published: (2005-08-01)

5-(4-Bromophenyl)-7-(2,4-dimethoxyphenyl)-4,7-dihydrotetrazolo[1,5-<em>a</em>]pyrimidine
by: Kautsar Ul Haq, et al.
Published: (2018-12-01)

Crystal structure of (RS)-(4-chlorophenyl)(pyridin-2-yl)methanol
by: Badiadka Narayana, et al.
Published: (2016-01-01)

rac-Ethyl 3-(3-bromo-2-thienyl)-2-oxo-6-(4-propoxyphenyl)cyclohex-3-ene-1-carboxylate
by: Andreas Fischer, et al.
Published: (2008-11-01)

(<em>R</em>,<em>S</em>)-5-(4-Chlorophenyl)-3-{(<em>E</em>)-2-[(<em>R</em>,<em>S</em>)-2,6,6-trimethylcyclohex-2-en-1-yl]vinyl}-4,5-dihydro-1<em>H</em>-pyrazole-1-carboximidamide Hydrochloride
by: Michele Cristina Carvalho, et al.
Published: (2019-02-01)

Crystal structure of 6-hydroxy-5-(2-methoxyphenoxy)-2,2′-bipyrimidin-4(3H)-one
by: Belakavadi K. Sagar, et al.
Published: (2016-07-01)

The crystal structures of three 3-methyl-1H-1,2,4-triazole-5-thiones, including a second polymorph of 4-[(E)-(5-bromo-2-hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione and a redetermination of 4-amino-3-methyl-1H-1,2,4-triazole-5(4H)-thione
by: Padmanabha S. Manjula, et al.
Published: (2015-09-01)

1-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazine
by: Chayanna Harish Chinthal, et al.
Published: (2020-11-01)

Crystal structures of three 6-aryl-2-(4-chlorobenzyl)-5-[(1H-indol-3-yl)methyl]imidazo[2,1-b][1,3,4]thiadiazoles
by: Sadashivamurthy Shamanth, et al.
Published: (2020-01-01)

Functionalized 3-(5-aryloxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)-1-(4-substituted-phenyl)prop-2-en-1-ones: synthetic pathway, and the structures of six examples
by: Haruvegowda Kiran Kumar, et al.
Published: (2020-05-01)

Synthesis of 1,3,4-Thiadiazole, 1,3,4-Thiadiazine, 1,3,6-Thiadiazepane and Quinoxaline Derivatives from Symmetrical Dithiobiureas and Thioureidoethylthiourea Derivatives
by: A. Abou-Zied, et al.
Published: (2005-08-01)

trans-Cyclohex-2-ene-1,4-diyl bis(4-nitrophenyl) dicarbonate
by: Syed Nawazish Ali, et al.
Published: (2008-01-01)

Crystal structure of 2-benzoylamino-N′-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide
by: Karanth N. Subbulakshmi, et al.
Published: (2016-08-01)

Di-tert-butyl cyclohex-2-ene-1,4-diyl dicarbonate
by: Syed Nawazish Ali, et al.
Published: (2009-11-01)

Ethyl 4-(2,4-dichlorophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate
by: B. Narayana, et al.
Published: (2010-10-01)

Syntheses and crystal structures of 4-(4-methoxyphenyl)piperazin-1-ium 4-methylbenzoate monohydrate and bis[4-(4-methoxyphenyl)piperazin-1-ium] benzene-1,2-dicarboxylate
by: Holehundi J. Shankara Prasad, et al.
Published: (2022-09-01)

A microwave approach to the synthesis of certain 4-substituted phenyl-6-phenyl-3-cyano-2-pyridones
by: Marinković Aleksandar, et al.
Published: (2014-01-01)

Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H...N, O—H...O and C—H...π(arene) hydrogen bonds
by: Marisiddaiah Girisha, et al.
Published: (2018-03-01)

Dimethyl 2-(3-chlorophenyl)-6-hydroxy-6-methyl-4-(methylamino)cyclohex-3-ene-1,3-dicarboxylate
by: S. Amirthaganesan, et al.
Published: (2011-06-01)

Microwave assisted synthesis of some novel acetazolamide cyclocondensed 1,2,3,4-tetrahydropyrimidines as a potent antimicrobial and cytotoxic agents
by: Karthikeyan Elumalai, et al.
Published: (2014-03-01)

1-[(Z)-2-Butyltellanyl-1-chloroethenyl]cyclohex-1-ene
by: Zukerman-Schpector, Julio, et al.
Published: (2012)

1-[(Z)-2-Butyltellanyl-1-chloroethenyl]cyclohex-1-ene
by: Edward R. T. Tiekink, et al.
Published: (2012-03-01)

Crystal and Molecular Structure Studies of Ethyl 4-(4-Hydroxyphenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate and Ethyl 4-(3-Bromophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate
by: Badiadka Narayana, et al.
Published: (2012-08-01)

Molecular shapes : theoretical models of inorganic stereochemistry/
by: 225187 Burdett, Jeremy K.
Published: (1980)

Formula stencil II: stereo-chemistry /
by: 426841 Schrader, B., et al.
Published: (1975)

Order and disorder in the world of atoms/
by: 225011 Kitaigorodskii, A. I.
Published: (1967)

(6Z)-3,5-Bis(4-fluorophenyl)-6-(1-hydroxyethylidene)cyclohex-2-en-1-one
by: H. S. Yathirajan, et al.
Published: (2012-03-01)

Synthesis of 5-(substituted phenylazo)-6-hydroxy-4-methyl-3-cyano-2-pyridones from ethyl 3-oxo-2-(substituted phenylazo)butanoates, Short communication
by: GORDANA UŠĆUMLIĆ, et al.
Published: (2011-04-01)

2-[(E)-(2,4,6-Trichlorophenyl)iminomethyl]phenol
by: Hoong-Kun Fun, et al.
Published: (2011-08-01)

An efficient synthesis of novel 3’-substituted 2-aryl-5-methyl-5'thioxo-[4,4'-bi-4H-1,2,4-triazol]-3(1'H, 2H)-ones
by: RAVINDRA R. KAMBLE, et al.
Published: (2006-04-01)

An efficient synthesis of novel 3’-substituted 2-aryl-5-methyl-5'thioxo-[4,4'-bi-4H-1,2,4-triazol]-3(1'H, 2H)-ones
by: Kamble Ravindra R., et al.
Published: (2006-01-01)

Synthesis of New trans-2-Benzyl-3-(furan-2-yl)-4-substituted-1,2,3,4-tetrahydroisoquinolinones
by: Mariana D. Palamareva, et al.
Published: (2006-06-01)

1-[(Z)-1-Bromo-2-(butyldichloro-&#955;4-tellanyl)ethenyl]cyclohex-1-ene
by: Julio Zukerman-Schpector, et al.
Published: (2011-07-01)