2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole
In the title compound, C16H12N2S2, the thiophene groups are rotationally disordered over two sets of sites, by approximately 180°, with occupancy ratios of 0.916 (2):0.084 (2) and 0.903 (2):0.097 (2). The major components of the th...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811055103 |
| _version_ | 1819290714647822336 |
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| author | David K. Geiger H. Cristina Geiger Leo Williams Bruce C. Noll |
| author_facet | David K. Geiger H. Cristina Geiger Leo Williams Bruce C. Noll |
| author_sort | David K. Geiger |
| collection | DOAJ |
| description | In the title compound, C16H12N2S2, the thiophene groups are rotationally disordered over two sets of sites, by approximately 180°, with occupancy ratios of 0.916 (2):0.084 (2) and 0.903 (2):0.097 (2). The major components of the thiophene and methylene substituted thiophene rings are canted by 24.06 (12) and 85.07 (10)°, respectively, from the benzimidazole ring system plane and the dihedral angle between the major component thiophene ring planes is 84.90 (14)°. In the crystal, there is a weak C—H...N hydrogen bond which links molecules into chains. |
| first_indexed | 2024-12-24T03:27:08Z |
| format | Article |
| id | doaj.art-2aa5cef4461a4a82b1a8a3919a54c371 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:27:08Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2aa5cef4461a4a82b1a8a3919a54c3712022-12-21T17:17:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682o420o42010.1107/S16005368110551032-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazoleDavid K. GeigerH. Cristina GeigerLeo WilliamsBruce C. NollIn the title compound, C16H12N2S2, the thiophene groups are rotationally disordered over two sets of sites, by approximately 180°, with occupancy ratios of 0.916 (2):0.084 (2) and 0.903 (2):0.097 (2). The major components of the thiophene and methylene substituted thiophene rings are canted by 24.06 (12) and 85.07 (10)°, respectively, from the benzimidazole ring system plane and the dihedral angle between the major component thiophene ring planes is 84.90 (14)°. In the crystal, there is a weak C—H...N hydrogen bond which links molecules into chains.http://scripts.iucr.org/cgi-bin/paper?S1600536811055103 |
| spellingShingle | David K. Geiger H. Cristina Geiger Leo Williams Bruce C. Noll 2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole Acta Crystallographica Section E |
| title | 2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole |
| title_full | 2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole |
| title_fullStr | 2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole |
| title_full_unstemmed | 2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole |
| title_short | 2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole |
| title_sort | 2 thiophen 2 yl 1 thiophen 2 ylmethyl 1h benzimidazole |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811055103 |
| work_keys_str_mv | AT davidkgeiger 2thiophen2yl1thiophen2ylmethyl1hbenzimidazole AT hcristinageiger 2thiophen2yl1thiophen2ylmethyl1hbenzimidazole AT leowilliams 2thiophen2yl1thiophen2ylmethyl1hbenzimidazole AT brucecnoll 2thiophen2yl1thiophen2ylmethyl1hbenzimidazole |