Grade-recovery beneficing and optimization of the froth flotation process of a mid-low phosphate ore using a mixed soybean and sunflower oil as a collector

In the phosphate industry, the use of certain flotation reagents can cause severe water pollution and have a negative effect on the environment and human health. Therefore, the development and utilization of eco-friendly flotation reagents are essential for the sustainable production of phosphate or...

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Main Authors: Zohra Farid, Mohamed Abdennouri, Noureddine Barka, M'hamed Sadiq
Format: Article
Language:English
Published: Elsevier 2022-10-01
Series:Applied Surface Science Advances
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666523922000770
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author Zohra Farid
Mohamed Abdennouri
Noureddine Barka
M'hamed Sadiq
author_facet Zohra Farid
Mohamed Abdennouri
Noureddine Barka
M'hamed Sadiq
author_sort Zohra Farid
collection DOAJ
description In the phosphate industry, the use of certain flotation reagents can cause severe water pollution and have a negative effect on the environment and human health. Therefore, the development and utilization of eco-friendly flotation reagents are essential for the sustainable production of phosphate ores and phosphate fertilizers. In this work, an economical and environmentally friendly mixed collector based on soybean and sunflower oils soaps was used to improve the grade and recovery of phosphate flotation. The results obtained from the flotation showed that the best composition of the mixed collector was 1:1 of the mass ratio of soybean and sunflower oils. In addition, the results showed that a low collector mass, medium solid content combined with an acidic medium resulted in a better relative floatability. Multi-response optimization was applied to optimize the process variables for both responses simultaneously using the Face Central Composite Design (FCCD). The effect of three independent variables such pH, collector mass, and solid content on the % P2O5 grade, and % recovery was studied. The results revealed that pH and collector mass had the most significant effect of the % grade response, while collector mass had a significant effect only on % recovery. It was found that more than 29.57% for grade content and 98.82% for the recovery can be achieved at the optimum conditions of low pH (pH 4) and low collector mass (0.13 g) and solid content (17.97 wt%). X-ray diffraction of the resulting solids confirms that the phosphate phase remains in the sink and that the gangue flows into the floated part.
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spelling doaj.art-2acb4fd4a5124d49bb7684b444bba8c72022-12-22T02:34:37ZengElsevierApplied Surface Science Advances2666-52392022-10-0111100287Grade-recovery beneficing and optimization of the froth flotation process of a mid-low phosphate ore using a mixed soybean and sunflower oil as a collectorZohra Farid0Mohamed Abdennouri1Noureddine Barka2M'hamed Sadiq3Sultan Moulay Slimane University of Beni Mellal, MRI lab, research group SEMA, FP Khouribga B.P. 145, 25000, MoroccoSultan Moulay Slimane University of Beni Mellal, MRI lab, research group SEMA, FP Khouribga B.P. 145, 25000, MoroccoSultan Moulay Slimane University of Beni Mellal, MRI lab, research group SEMA, FP Khouribga B.P. 145, 25000, MoroccoCorresponding author.; Sultan Moulay Slimane University of Beni Mellal, MRI lab, research group SEMA, FP Khouribga B.P. 145, 25000, MoroccoIn the phosphate industry, the use of certain flotation reagents can cause severe water pollution and have a negative effect on the environment and human health. Therefore, the development and utilization of eco-friendly flotation reagents are essential for the sustainable production of phosphate ores and phosphate fertilizers. In this work, an economical and environmentally friendly mixed collector based on soybean and sunflower oils soaps was used to improve the grade and recovery of phosphate flotation. The results obtained from the flotation showed that the best composition of the mixed collector was 1:1 of the mass ratio of soybean and sunflower oils. In addition, the results showed that a low collector mass, medium solid content combined with an acidic medium resulted in a better relative floatability. Multi-response optimization was applied to optimize the process variables for both responses simultaneously using the Face Central Composite Design (FCCD). The effect of three independent variables such pH, collector mass, and solid content on the % P2O5 grade, and % recovery was studied. The results revealed that pH and collector mass had the most significant effect of the % grade response, while collector mass had a significant effect only on % recovery. It was found that more than 29.57% for grade content and 98.82% for the recovery can be achieved at the optimum conditions of low pH (pH 4) and low collector mass (0.13 g) and solid content (17.97 wt%). X-ray diffraction of the resulting solids confirms that the phosphate phase remains in the sink and that the gangue flows into the floated part.http://www.sciencedirect.com/science/article/pii/S2666523922000770Phosphate flotationSoybean oilSunflower oilFace central composite design
spellingShingle Zohra Farid
Mohamed Abdennouri
Noureddine Barka
M'hamed Sadiq
Grade-recovery beneficing and optimization of the froth flotation process of a mid-low phosphate ore using a mixed soybean and sunflower oil as a collector
Applied Surface Science Advances
Phosphate flotation
Soybean oil
Sunflower oil
Face central composite design
title Grade-recovery beneficing and optimization of the froth flotation process of a mid-low phosphate ore using a mixed soybean and sunflower oil as a collector
title_full Grade-recovery beneficing and optimization of the froth flotation process of a mid-low phosphate ore using a mixed soybean and sunflower oil as a collector
title_fullStr Grade-recovery beneficing and optimization of the froth flotation process of a mid-low phosphate ore using a mixed soybean and sunflower oil as a collector
title_full_unstemmed Grade-recovery beneficing and optimization of the froth flotation process of a mid-low phosphate ore using a mixed soybean and sunflower oil as a collector
title_short Grade-recovery beneficing and optimization of the froth flotation process of a mid-low phosphate ore using a mixed soybean and sunflower oil as a collector
title_sort grade recovery beneficing and optimization of the froth flotation process of a mid low phosphate ore using a mixed soybean and sunflower oil as a collector
topic Phosphate flotation
Soybean oil
Sunflower oil
Face central composite design
url http://www.sciencedirect.com/science/article/pii/S2666523922000770
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