Zinc Removal from Water via EDTA-Modified Mesoporous SBA-16 and SBA-15

The removal of zinc ions from water was investigated using two types of ordered mesoporous silica (SBA-15 and SBA-16). Both materials were functionalized with APTES (3-aminopropyltriethoxy-silane) and EDTA (ethylenediaminetetraacetic acid) through post grafting methods. The modified adsorbents were...

Full description

Bibliographic Details
Main Authors: Zeinab Ezzeddine, Isabelle Batonneau-Gener, Yannick Pouilloux
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Toxics
Subjects:
Online Access:https://www.mdpi.com/2305-6304/11/3/205
Description
Summary:The removal of zinc ions from water was investigated using two types of ordered mesoporous silica (SBA-15 and SBA-16). Both materials were functionalized with APTES (3-aminopropyltriethoxy-silane) and EDTA (ethylenediaminetetraacetic acid) through post grafting methods. The modified adsorbents were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), X-ray diffraction (XRD), nitrogen (N<sub>2</sub>) adsorption–desorption analysis, Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis. The ordered structure of the adsorbents was conserved after modification. SBA-16 was found to be more efficient than SBA-15 owing to its structural characteristics. Different experimental conditions were examined (pH, contact time, and initial zinc concentration). The kinetic adsorption data followed the pseudo-second-order model indicating favorable adsorption conditions. The intra-particle diffusion model plot represented a two-stage adsorption process. The maximum adsorption capacities were calculated by the Langmuir model. The adsorbent can be regenerated and reused several times without a significant decline in adsorption efficiency.
ISSN:2305-6304