Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization
Heterogenization of the photocatalyst appears to be a valuable solution to reach sustainable processes. Rapid and efficient synthesis of supported photocatalyst is still a remaining challenge and the choice of the support material is crucial. The present study aims at preparing a new generation of h...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-01-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/28/2/549 |
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| author | Nadine Mahmoud Jazia Awassa Joumana Toufaily Bénédicte Lebeau T. Jean Daou Morgan Cormier Jean-Philippe Goddard |
| author_facet | Nadine Mahmoud Jazia Awassa Joumana Toufaily Bénédicte Lebeau T. Jean Daou Morgan Cormier Jean-Philippe Goddard |
| author_sort | Nadine Mahmoud |
| collection | DOAJ |
| description | Heterogenization of the photocatalyst appears to be a valuable solution to reach sustainable processes. Rapid and efficient synthesis of supported photocatalyst is still a remaining challenge and the choice of the support material is crucial. The present study aims at preparing a new generation of hybrid inorganic/organic photocatalysts based on silica mesoporous material and Eosin Y. These results highlight the influence of non-covalent interactions between the material support and the reagent impacting the selectivity of the reaction. |
| first_indexed | 2024-03-09T11:35:41Z |
| format | Article |
| id | doaj.art-2af9f0d6ec4547fdb1324322b362830d |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T11:35:41Z |
| publishDate | 2023-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-2af9f0d6ec4547fdb1324322b362830d2023-11-30T23:41:25ZengMDPI AGMolecules1420-30492023-01-0128254910.3390/molecules28020549Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical CyclizationNadine Mahmoud0Jazia Awassa1Joumana Toufaily2Bénédicte Lebeau3T. Jean Daou4Morgan Cormier5Jean-Philippe Goddard6Université de Haute-Alsace (UHA), Université de Strasbourg, CNRS, Laboratoire d’Innovation Moléculaire et Applications (LIMA) UMR 7042, 68100 Mulhouse, FranceUniversité de Haute-Alsace (UHA), Université de Strasbourg, CNRS, Laboratoire d’Innovation Moléculaire et Applications (LIMA) UMR 7042, 68100 Mulhouse, FranceLaboratory of Materials, Catalysis, Environment and Analytical Methods, Faculty of Sciences I, Lebanese University, Campus Rafic Hariri, Beyrouth, LebanonUniversité de Haute Alsace, CNRS, IS2M, UMR 7361, 68100 Mulhouse, FranceUniversité de Haute Alsace, CNRS, IS2M, UMR 7361, 68100 Mulhouse, FranceUniversité de Haute-Alsace (UHA), Université de Strasbourg, CNRS, Laboratoire d’Innovation Moléculaire et Applications (LIMA) UMR 7042, 68100 Mulhouse, FranceUniversité de Haute-Alsace (UHA), Université de Strasbourg, CNRS, Laboratoire d’Innovation Moléculaire et Applications (LIMA) UMR 7042, 68100 Mulhouse, FranceHeterogenization of the photocatalyst appears to be a valuable solution to reach sustainable processes. Rapid and efficient synthesis of supported photocatalyst is still a remaining challenge and the choice of the support material is crucial. The present study aims at preparing a new generation of hybrid inorganic/organic photocatalysts based on silica mesoporous material and Eosin Y. These results highlight the influence of non-covalent interactions between the material support and the reagent impacting the selectivity of the reaction.https://www.mdpi.com/1420-3049/28/2/549heterogeneous photoredox catalysismesoporous silica materialaza-Henry reaction[2+2] cycloadditionhybrid organic-inorganic material |
| spellingShingle | Nadine Mahmoud Jazia Awassa Joumana Toufaily Bénédicte Lebeau T. Jean Daou Morgan Cormier Jean-Philippe Goddard Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization Molecules heterogeneous photoredox catalysis mesoporous silica material aza-Henry reaction [2+2] cycloaddition hybrid organic-inorganic material |
| title | Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization |
| title_full | Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization |
| title_fullStr | Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization |
| title_full_unstemmed | Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization |
| title_short | Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization |
| title_sort | heterogeneous photoredox catalysis based on silica mesoporous material and eosin y impact of material support on selectivity of radical cyclization |
| topic | heterogeneous photoredox catalysis mesoporous silica material aza-Henry reaction [2+2] cycloaddition hybrid organic-inorganic material |
| url | https://www.mdpi.com/1420-3049/28/2/549 |
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