Thiocyanatochrome complexes in analytical chemistry: Determination of osmium(III)

New complex combinations of Os(III) complexed with thiourea and ethyl thiourea, as well as of complex anions of Cr(III) analogues of Reineke’s salt, [Cr(CNS)4(amine)2]-, where the amine is aniline, benzylamine morpholine etc., were synthesized. New gravimetric, oxidimetric and spectrophotometric ana...

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Bibliographic Details
Main Authors: Bratulescu George, Ganescu Ion, Ganescu Anca
Format: Article
Language:English
Published: Serbian Chemical Society 2005-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2005/0352-51390509113B.pdf
Description
Summary:New complex combinations of Os(III) complexed with thiourea and ethyl thiourea, as well as of complex anions of Cr(III) analogues of Reineke’s salt, [Cr(CNS)4(amine)2]-, where the amine is aniline, benzylamine morpholine etc., were synthesized. New gravimetric, oxidimetric and spectrophotometric analytical methods are proposed for the determination of Os(III). The experimental data were statistically processed and are not affected by systematic errors.
ISSN:0352-5139
1820-7421