Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions
Diarylamines were synthesized using p-toluene sulfonamides with benzhydrol derivatives in the presence of a copper/bisphosphine complex by Borrowing Hydrogen (BH) mechanism, yielding ${<}98\%$ under clean and mild reaction conditions. The use of readily available and cost-effective copper salts,...
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| Format: | Article |
| Language: | English |
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Académie des sciences
2020-05-01
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| Series: | Comptes Rendus. Chimie |
| Subjects: | |
| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.5/ |
| _version_ | 1797651367240663040 |
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| author | Ashouri, Akram Samadi, Saadi Ahmadian, Masoud Nasiri, Behzad |
| author_facet | Ashouri, Akram Samadi, Saadi Ahmadian, Masoud Nasiri, Behzad |
| author_sort | Ashouri, Akram |
| collection | DOAJ |
| description | Diarylamines were synthesized using p-toluene sulfonamides with benzhydrol derivatives in the presence of a copper/bisphosphine complex by Borrowing Hydrogen (BH) mechanism, yielding ${<}98\%$ under clean and mild reaction conditions. The use of readily available and cost-effective copper salts, short reaction times, high yield and reaction rates are highlighted. |
| first_indexed | 2024-03-11T16:14:57Z |
| format | Article |
| id | doaj.art-2b38bb1d198e4f77930a52fb91907517 |
| institution | Directory Open Access Journal |
| issn | 1878-1543 |
| language | English |
| last_indexed | 2024-03-11T16:14:57Z |
| publishDate | 2020-05-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj.art-2b38bb1d198e4f77930a52fb919075172023-10-24T14:22:36ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432020-05-01231475510.5802/crchim.510.5802/crchim.5Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditionsAshouri, Akram0Samadi, Saadi1Ahmadian, Masoud2Nasiri, Behzad3https://orcid.org/0000-0002-5119-0356Laboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15175, Sanandaj, IranLaboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15175, Sanandaj, IranLaboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15175, Sanandaj, IranLaboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15175, Sanandaj, IranDiarylamines were synthesized using p-toluene sulfonamides with benzhydrol derivatives in the presence of a copper/bisphosphine complex by Borrowing Hydrogen (BH) mechanism, yielding ${<}98\%$ under clean and mild reaction conditions. The use of readily available and cost-effective copper salts, short reaction times, high yield and reaction rates are highlighted.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.5/Diaryl amineBenzhydrolsulfonamidesCopper saltBisphosphine ligandsBorrowing Hydrogen (BH) mechanism |
| spellingShingle | Ashouri, Akram Samadi, Saadi Ahmadian, Masoud Nasiri, Behzad Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions Comptes Rendus. Chimie Diaryl amine Benzhydrol sulfonamides Copper salt Bisphosphine ligands Borrowing Hydrogen (BH) mechanism |
| title | Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions |
| title_full | Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions |
| title_fullStr | Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions |
| title_full_unstemmed | Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions |
| title_short | Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions |
| title_sort | copper catalyzed synthesis of diarylamines using p toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions |
| topic | Diaryl amine Benzhydrol sulfonamides Copper salt Bisphosphine ligands Borrowing Hydrogen (BH) mechanism |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.5/ |
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