Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ3N2,N1,N6)manganese(II) iodide monohydrate
The asymmetric unit of the title compound, [MnI(C24H16N6)(H2O)2]I·H2O, consists of a cationic MnII complex, an I− anion and a solvent water molecule. In the complex, the MnII ion is six-coordinated in a considerably distorted octahedral environment defined by three N atoms...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811035434 |
| _version_ | 1798025750766419968 |
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| author | Kwang Ha |
| author_facet | Kwang Ha |
| author_sort | Kwang Ha |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [MnI(C24H16N6)(H2O)2]I·H2O, consists of a cationic MnII complex, an I− anion and a solvent water molecule. In the complex, the MnII ion is six-coordinated in a considerably distorted octahedral environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridylpyrazine (tppz) ligand, one I− anion and two O atoms of two water ligands. The dihedral angles between the pyridyl rings [maximum deviation = 0.034 (6) Å] and their carrier pyrazine ring [maximum deviation = 0.020 (6) Å] are 26.5 (2) and 27.0 (2)° for the coordinated pyridyl rings, and 51.3 (3) and 43.2 (2)° for the uncoordinated pyridyl rings. Intermolecular O—H...O, O—H...N and O—H...I hydrogen bonds stabilize the crystal structure. |
| first_indexed | 2024-04-11T18:23:58Z |
| format | Article |
| id | doaj.art-2b3d7d3f76a54e9c87ef8de4706f0a68 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:23:58Z |
| publishDate | 2011-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2b3d7d3f76a54e9c87ef8de4706f0a682022-12-22T04:09:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1333m133310.1107/S1600536811035434Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ3N2,N1,N6)manganese(II) iodide monohydrateKwang HaThe asymmetric unit of the title compound, [MnI(C24H16N6)(H2O)2]I·H2O, consists of a cationic MnII complex, an I− anion and a solvent water molecule. In the complex, the MnII ion is six-coordinated in a considerably distorted octahedral environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridylpyrazine (tppz) ligand, one I− anion and two O atoms of two water ligands. The dihedral angles between the pyridyl rings [maximum deviation = 0.034 (6) Å] and their carrier pyrazine ring [maximum deviation = 0.020 (6) Å] are 26.5 (2) and 27.0 (2)° for the coordinated pyridyl rings, and 51.3 (3) and 43.2 (2)° for the uncoordinated pyridyl rings. Intermolecular O—H...O, O—H...N and O—H...I hydrogen bonds stabilize the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811035434 |
| spellingShingle | Kwang Ha Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ3N2,N1,N6)manganese(II) iodide monohydrate Acta Crystallographica Section E |
| title | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ3N2,N1,N6)manganese(II) iodide monohydrate |
| title_full | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ3N2,N1,N6)manganese(II) iodide monohydrate |
| title_fullStr | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ3N2,N1,N6)manganese(II) iodide monohydrate |
| title_full_unstemmed | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ3N2,N1,N6)manganese(II) iodide monohydrate |
| title_short | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ3N2,N1,N6)manganese(II) iodide monohydrate |
| title_sort | diaquaiodido 2 3 5 6 tetra 2 pyridylpyrazine amp 954 3n2 n1 n6 manganese ii iodide monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811035434 |
| work_keys_str_mv | AT kwangha diaquaiodido2356tetra2pyridylpyrazineamp9543n2n1n6manganeseiiiodidemonohydrate |