Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ2O1:O1′]magnesium] 0.4-hydrate]
In the title compound, {[Mg(C8H6FO3)2(H2O)2]·0.4H2O}n, slightly distorted octahedral MgO6 complex units have crystallographic inversion symmetry, the coordination polyhedron comprising two trans-related water molecules and four carboxyl O-atom donors, two of which are bridging. Within t...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812035246 |
| _version_ | 1819294639163703296 |
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| author | Graham Smith |
| author_facet | Graham Smith |
| author_sort | Graham Smith |
| collection | DOAJ |
| description | In the title compound, {[Mg(C8H6FO3)2(H2O)2]·0.4H2O}n, slightly distorted octahedral MgO6 complex units have crystallographic inversion symmetry, the coordination polyhedron comprising two trans-related water molecules and four carboxyl O-atom donors, two of which are bridging. Within the two-dimensional complex polymer which is parallel to (100), coordinating water molecules form intermolecular O—H...O hydrogen bonds with carboxylate and phenoxy O-atom acceptors, as well as with the partial-occupancy solvent water molecules. |
| first_indexed | 2024-12-24T04:29:31Z |
| format | Article |
| id | doaj.art-2b45f53dbca44b068fc9c862a84b892c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T04:29:31Z |
| publishDate | 2012-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2b45f53dbca44b068fc9c862a84b892c2022-12-21T17:15:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1178m117810.1107/S1600536812035246Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ2O1:O1′]magnesium] 0.4-hydrate]Graham SmithIn the title compound, {[Mg(C8H6FO3)2(H2O)2]·0.4H2O}n, slightly distorted octahedral MgO6 complex units have crystallographic inversion symmetry, the coordination polyhedron comprising two trans-related water molecules and four carboxyl O-atom donors, two of which are bridging. Within the two-dimensional complex polymer which is parallel to (100), coordinating water molecules form intermolecular O—H...O hydrogen bonds with carboxylate and phenoxy O-atom acceptors, as well as with the partial-occupancy solvent water molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536812035246 |
| spellingShingle | Graham Smith Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ2O1:O1′]magnesium] 0.4-hydrate] Acta Crystallographica Section E |
| title | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ2O1:O1′]magnesium] 0.4-hydrate] |
| title_full | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ2O1:O1′]magnesium] 0.4-hydrate] |
| title_fullStr | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ2O1:O1′]magnesium] 0.4-hydrate] |
| title_full_unstemmed | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ2O1:O1′]magnesium] 0.4-hydrate] |
| title_short | Poly[[diaquabis[μ-2-(4-fluorophenoxy)acetato-κ2O1:O1′]magnesium] 0.4-hydrate] |
| title_sort | poly diaquabis amp 956 2 4 fluorophenoxy acetato amp 954 2o1 o1 amp 8242 magnesium 0 4 hydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812035246 |
| work_keys_str_mv | AT grahamsmith polydiaquabisamp95624fluorophenoxyacetatoamp9542o1o1amp8242magnesium04hydrate |