Compositionally Disordered Crystalline Compounds for Next Generation of Radiation Detectors

The review is devoted to the analysis of the compositional disordering potential of the crystal matrix of a scintillator to improve its scintillation parameters. Technological capabilities to complicate crystal matrices both in anionic and cationic sublattices of a variety of compounds are examined....

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Main Authors: Vasili Retivov, Valery Dubov, Ilia Komendo, Petr Karpyuk, Daria Kuznetsova, Petr Sokolov, Yauheni Talochka, Mikhail Korzhik
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/12/23/4295
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author Vasili Retivov
Valery Dubov
Ilia Komendo
Petr Karpyuk
Daria Kuznetsova
Petr Sokolov
Yauheni Talochka
Mikhail Korzhik
author_facet Vasili Retivov
Valery Dubov
Ilia Komendo
Petr Karpyuk
Daria Kuznetsova
Petr Sokolov
Yauheni Talochka
Mikhail Korzhik
author_sort Vasili Retivov
collection DOAJ
description The review is devoted to the analysis of the compositional disordering potential of the crystal matrix of a scintillator to improve its scintillation parameters. Technological capabilities to complicate crystal matrices both in anionic and cationic sublattices of a variety of compounds are examined. The effects of the disorder at nano-level on the landscape at the bottom of the conduction band, which is adjacent to the band gap, have been discussed. The ways to control the composition of polycationic compounds when creating precursors, the role of disorder in the anionic sublattice in alkali halide compounds, a positive role of Gd based matrices on scintillation properties, and the control of the heterovalent state of the activator by creation of disorder in silicates have been considered as well. The benefits of introducing a 3D printing method, which is prospective for the engineering and production of scintillators at the nanoscale level, have been manifested.
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spelling doaj.art-2b5a57f39ca445fa840e0a9b82c7b35c2023-11-24T11:48:39ZengMDPI AGNanomaterials2079-49912022-12-011223429510.3390/nano12234295Compositionally Disordered Crystalline Compounds for Next Generation of Radiation DetectorsVasili Retivov0Valery Dubov1Ilia Komendo2Petr Karpyuk3Daria Kuznetsova4Petr Sokolov5Yauheni Talochka6Mikhail Korzhik7National Research Center “Kurchatov Institute”, Moscow 123098, RussiaNational Research Center “Kurchatov Institute”, Moscow 123098, RussiaNational Research Center “Kurchatov Institute”, Moscow 123098, RussiaNational Research Center “Kurchatov Institute”, Moscow 123098, RussiaNational Research Center “Kurchatov Institute”, Moscow 123098, RussiaNational Research Center “Kurchatov Institute”—Institute of Reactives, IREA, Moscow 107076, RussiaInstitute for Nuclear Problems, Belarus State University, 220030 Minsk, BelarusNational Research Center “Kurchatov Institute”, Moscow 123098, RussiaThe review is devoted to the analysis of the compositional disordering potential of the crystal matrix of a scintillator to improve its scintillation parameters. Technological capabilities to complicate crystal matrices both in anionic and cationic sublattices of a variety of compounds are examined. The effects of the disorder at nano-level on the landscape at the bottom of the conduction band, which is adjacent to the band gap, have been discussed. The ways to control the composition of polycationic compounds when creating precursors, the role of disorder in the anionic sublattice in alkali halide compounds, a positive role of Gd based matrices on scintillation properties, and the control of the heterovalent state of the activator by creation of disorder in silicates have been considered as well. The benefits of introducing a 3D printing method, which is prospective for the engineering and production of scintillators at the nanoscale level, have been manifested.https://www.mdpi.com/2079-4991/12/23/4295inorganic compoundcrystalline materialscintillatorcompositional disorderlight yieldscintillation kinetics
spellingShingle Vasili Retivov
Valery Dubov
Ilia Komendo
Petr Karpyuk
Daria Kuznetsova
Petr Sokolov
Yauheni Talochka
Mikhail Korzhik
Compositionally Disordered Crystalline Compounds for Next Generation of Radiation Detectors
Nanomaterials
inorganic compound
crystalline material
scintillator
compositional disorder
light yield
scintillation kinetics
title Compositionally Disordered Crystalline Compounds for Next Generation of Radiation Detectors
title_full Compositionally Disordered Crystalline Compounds for Next Generation of Radiation Detectors
title_fullStr Compositionally Disordered Crystalline Compounds for Next Generation of Radiation Detectors
title_full_unstemmed Compositionally Disordered Crystalline Compounds for Next Generation of Radiation Detectors
title_short Compositionally Disordered Crystalline Compounds for Next Generation of Radiation Detectors
title_sort compositionally disordered crystalline compounds for next generation of radiation detectors
topic inorganic compound
crystalline material
scintillator
compositional disorder
light yield
scintillation kinetics
url https://www.mdpi.com/2079-4991/12/23/4295
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