Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy
Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy (FO-QEPA-PTS) is reported for the first time. In FO-QEPA-PTS, the detection of the photoacoustic and photothermal hybrid signal is achieved through the use of a custom quartz tuning fork (QTF), thereby mitigating...
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Language: | English |
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Elsevier
2024-02-01
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Series: | Photoacoustics |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2213597923001337 |
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author | Ruyue Cui Hongpeng Wu Frank K. Tittel Vincenzo Spagnolo Weidong Chen Lei Dong |
author_facet | Ruyue Cui Hongpeng Wu Frank K. Tittel Vincenzo Spagnolo Weidong Chen Lei Dong |
author_sort | Ruyue Cui |
collection | DOAJ |
description | Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy (FO-QEPA-PTS) is reported for the first time. In FO-QEPA-PTS, the detection of the photoacoustic and photothermal hybrid signal is achieved through the use of a custom quartz tuning fork (QTF), thereby mitigating the issue of resonant frequency mismatch typically encountered in quartz-enhanced photoacoustic-photothermal spectroscopy employing multiple QTFs. A multi-laser beam, created by a multi-pass cell (MPC) with a designed single-line spot pattern, partially strikes the inner edge of the QTF and partially passes through the prong of the QTF, thereby generating photoacoustic and photothermal hybrid signals. To assess the performance of FO-QEPA-PTS, 1 % acetylene is selected as the analyte gas and the 2f signals produced by the photoacoustic, the photothermal, and their hybrid effects are measured. Comparative analysis against QEPAS and QEPTS reveals signal gain factors of ∼ 79 and ∼ 14, respectively, when these laser beams created by MPC excite the QTF operating at fundamental resonance mode in phase. In the FO-QEPA-PTS signal, the proportions of the photoacoustic and the photothermal effects induced by the multiple beams are ∼7 % and 93 %, respectively. |
first_indexed | 2024-03-08T12:08:26Z |
format | Article |
id | doaj.art-2bae9da014914d7e9cc03dd2b5785b4d |
institution | Directory Open Access Journal |
issn | 2213-5979 |
language | English |
last_indexed | 2024-03-08T12:08:26Z |
publishDate | 2024-02-01 |
publisher | Elsevier |
record_format | Article |
series | Photoacoustics |
spelling | doaj.art-2bae9da014914d7e9cc03dd2b5785b4d2024-01-23T04:15:37ZengElsevierPhotoacoustics2213-59792024-02-0135100580Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopyRuyue Cui0Hongpeng Wu1Frank K. Tittel2Vincenzo Spagnolo3Weidong Chen4Lei Dong5State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, China; Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, China; Laboratoire de Physicochimie de l′Atmosphère, Université du Littoral Côte d′Opale, Dunkerque 59140, FranceCorresponding author.; State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, China; Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, ChinaDepartment of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, TX 77005, USAState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, China; PolySense Lab-Dipartimento Interateneo di Fisica, University and Politecnico of Bari, Via Amendola 173, Bari, ItalyLaboratoire de Physicochimie de l′Atmosphère, Université du Littoral Côte d′Opale, Dunkerque 59140, FranceCorresponding author.; State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, China; Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, ChinaFolded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy (FO-QEPA-PTS) is reported for the first time. In FO-QEPA-PTS, the detection of the photoacoustic and photothermal hybrid signal is achieved through the use of a custom quartz tuning fork (QTF), thereby mitigating the issue of resonant frequency mismatch typically encountered in quartz-enhanced photoacoustic-photothermal spectroscopy employing multiple QTFs. A multi-laser beam, created by a multi-pass cell (MPC) with a designed single-line spot pattern, partially strikes the inner edge of the QTF and partially passes through the prong of the QTF, thereby generating photoacoustic and photothermal hybrid signals. To assess the performance of FO-QEPA-PTS, 1 % acetylene is selected as the analyte gas and the 2f signals produced by the photoacoustic, the photothermal, and their hybrid effects are measured. Comparative analysis against QEPAS and QEPTS reveals signal gain factors of ∼ 79 and ∼ 14, respectively, when these laser beams created by MPC excite the QTF operating at fundamental resonance mode in phase. In the FO-QEPA-PTS signal, the proportions of the photoacoustic and the photothermal effects induced by the multiple beams are ∼7 % and 93 %, respectively.http://www.sciencedirect.com/science/article/pii/S2213597923001337Photoacoustic spectroscopyPhotothermal spectroscopyMulti-pass cellQuartz tuning fork |
spellingShingle | Ruyue Cui Hongpeng Wu Frank K. Tittel Vincenzo Spagnolo Weidong Chen Lei Dong Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy Photoacoustics Photoacoustic spectroscopy Photothermal spectroscopy Multi-pass cell Quartz tuning fork |
title | Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy |
title_full | Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy |
title_fullStr | Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy |
title_full_unstemmed | Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy |
title_short | Folded-optics-based quartz-enhanced photoacoustic and photothermal hybrid spectroscopy |
title_sort | folded optics based quartz enhanced photoacoustic and photothermal hybrid spectroscopy |
topic | Photoacoustic spectroscopy Photothermal spectroscopy Multi-pass cell Quartz tuning fork |
url | http://www.sciencedirect.com/science/article/pii/S2213597923001337 |
work_keys_str_mv | AT ruyuecui foldedopticsbasedquartzenhancedphotoacousticandphotothermalhybridspectroscopy AT hongpengwu foldedopticsbasedquartzenhancedphotoacousticandphotothermalhybridspectroscopy AT frankktittel foldedopticsbasedquartzenhancedphotoacousticandphotothermalhybridspectroscopy AT vincenzospagnolo foldedopticsbasedquartzenhancedphotoacousticandphotothermalhybridspectroscopy AT weidongchen foldedopticsbasedquartzenhancedphotoacousticandphotothermalhybridspectroscopy AT leidong foldedopticsbasedquartzenhancedphotoacousticandphotothermalhybridspectroscopy |