Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment
The adsorptive removal of dyes from industrial wastewater using commercially available adsorbents is not significantly efficient. Metal–organic frameworks (MOFs) offer outstanding properties which can boost the separation performance over current commercial adsorbents and hence, these materials repr...
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| Format: | Article |
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MDPI AG
2022-03-01
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| Series: | Energies |
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| Online Access: | https://www.mdpi.com/1996-1073/15/6/2023 |
| _version_ | 1797471778610610176 |
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| author | Mohammadreza Beydaghdari Fahimeh Hooriabad Saboor Aziz Babapoor Vikram V. Karve Mehrdad Asgari |
| author_facet | Mohammadreza Beydaghdari Fahimeh Hooriabad Saboor Aziz Babapoor Vikram V. Karve Mehrdad Asgari |
| author_sort | Mohammadreza Beydaghdari |
| collection | DOAJ |
| description | The adsorptive removal of dyes from industrial wastewater using commercially available adsorbents is not significantly efficient. Metal–organic frameworks (MOFs) offer outstanding properties which can boost the separation performance over current commercial adsorbents and hence, these materials represent a milestone in improving treatment methods for dye removal from water. Accordingly, in this paper, the recent studies in the modification of MOF structures in dye removal from the aquatic environment have been discussed. This study aims to elaborate on the synthetic strategies applied to improve the adsorption efficiency and to discuss the major adsorption mechanisms as well as the most influential parameters in the adsorptive removal of dyes using MOFs. More particularly, the advanced separation performance of MOF-based adsorbents will be comprehensively explained. The introduction of various functional groups and nanomaterials, such as amine functional groups, magnetic nanoparticles, and carbon-based materials such as graphene oxide and CNT, onto the MOFs can alter the removal efficiency of MOF-based adsorbents through enhancing the water stability, dispersion in water, interactions between the MOF structure and the contaminant, and the adsorption capacity. Finally, we summarize the challenges experienced by MOF-based materials for dye removal from water and propose future research outlooks to be considered. |
| first_indexed | 2024-03-09T19:53:52Z |
| format | Article |
| id | doaj.art-2bb06b8569ae49e7b5f8b698db1b6d1d |
| institution | Directory Open Access Journal |
| issn | 1996-1073 |
| language | English |
| last_indexed | 2024-03-09T19:53:52Z |
| publishDate | 2022-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Energies |
| spelling | doaj.art-2bb06b8569ae49e7b5f8b698db1b6d1d2023-11-24T01:03:23ZengMDPI AGEnergies1996-10732022-03-01156202310.3390/en15062023Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic EnvironmentMohammadreza Beydaghdari0Fahimeh Hooriabad Saboor1Aziz Babapoor2Vikram V. Karve3Mehrdad Asgari4Department of Chemical Engineering, Faculty of Engineering, University of Mohaghegh Ardabili, Ardabil 56199-11367, IranDepartment of Chemical Engineering, Faculty of Engineering, University of Mohaghegh Ardabili, Ardabil 56199-11367, IranDepartment of Chemical Engineering, Faculty of Engineering, University of Mohaghegh Ardabili, Ardabil 56199-11367, IranInstitute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), CH-1951 Sion, SwitzerlandInstitute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), CH-1951 Sion, SwitzerlandThe adsorptive removal of dyes from industrial wastewater using commercially available adsorbents is not significantly efficient. Metal–organic frameworks (MOFs) offer outstanding properties which can boost the separation performance over current commercial adsorbents and hence, these materials represent a milestone in improving treatment methods for dye removal from water. Accordingly, in this paper, the recent studies in the modification of MOF structures in dye removal from the aquatic environment have been discussed. This study aims to elaborate on the synthetic strategies applied to improve the adsorption efficiency and to discuss the major adsorption mechanisms as well as the most influential parameters in the adsorptive removal of dyes using MOFs. More particularly, the advanced separation performance of MOF-based adsorbents will be comprehensively explained. The introduction of various functional groups and nanomaterials, such as amine functional groups, magnetic nanoparticles, and carbon-based materials such as graphene oxide and CNT, onto the MOFs can alter the removal efficiency of MOF-based adsorbents through enhancing the water stability, dispersion in water, interactions between the MOF structure and the contaminant, and the adsorption capacity. Finally, we summarize the challenges experienced by MOF-based materials for dye removal from water and propose future research outlooks to be considered.https://www.mdpi.com/1996-1073/15/6/2023adsorptive separationdye removalfunctionalized MOFMOF compositewater treatment |
| spellingShingle | Mohammadreza Beydaghdari Fahimeh Hooriabad Saboor Aziz Babapoor Vikram V. Karve Mehrdad Asgari Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment Energies adsorptive separation dye removal functionalized MOF MOF composite water treatment |
| title | Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment |
| title_full | Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment |
| title_fullStr | Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment |
| title_full_unstemmed | Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment |
| title_short | Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment |
| title_sort | recent advances in mof based adsorbents for dye removal from the aquatic environment |
| topic | adsorptive separation dye removal functionalized MOF MOF composite water treatment |
| url | https://www.mdpi.com/1996-1073/15/6/2023 |
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