(4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(dibenzoylmethanido-κ2O,O′)bis(nitrato-κ2O,O′)neodymium(III) acetonitrile solvate
The title complex, [Nd(C15H11O2)(NO3)2(C18H15N3O)]·CH3CN or [Nd(altpy)(dbm)(NO3)2]·CH3CN (altpy = 4′-allyloxy-2,2′:6′,2′′-terpyridine, dbm = dibenzoylmethanide anion), has been synthesized from 4&...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680905185X |
| _version_ | 1819279935369379840 |
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| author | Qunbo Mei Bihai Tong |
| author_facet | Qunbo Mei Bihai Tong |
| author_sort | Qunbo Mei |
| collection | DOAJ |
| description | The title complex, [Nd(C15H11O2)(NO3)2(C18H15N3O)]·CH3CN or [Nd(altpy)(dbm)(NO3)2]·CH3CN (altpy = 4′-allyloxy-2,2′:6′,2′′-terpyridine, dbm = dibenzoylmethanide anion), has been synthesized from 4′-allyloxy-2,2′:6′,2′′-terpyridine, dibenzoylmethanate and neodymium nitrate. The Nd3+ atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four O atoms from two nitrate anions that act as bidentate ligands and occupy mutually trans sites in a distorted monocapped square-antiprismatic geometry. |
| first_indexed | 2024-12-24T00:35:48Z |
| format | Article |
| id | doaj.art-2bb1e564e1be4fb3a8b1c26f0c6c006f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:35:48Z |
| publishDate | 2010-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2bb1e564e1be4fb3a8b1c26f0c6c006f2022-12-21T17:24:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m18m1810.1107/S160053680905185X(4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(dibenzoylmethanido-κ2O,O′)bis(nitrato-κ2O,O′)neodymium(III) acetonitrile solvateQunbo MeiBihai TongThe title complex, [Nd(C15H11O2)(NO3)2(C18H15N3O)]·CH3CN or [Nd(altpy)(dbm)(NO3)2]·CH3CN (altpy = 4′-allyloxy-2,2′:6′,2′′-terpyridine, dbm = dibenzoylmethanide anion), has been synthesized from 4′-allyloxy-2,2′:6′,2′′-terpyridine, dibenzoylmethanate and neodymium nitrate. The Nd3+ atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four O atoms from two nitrate anions that act as bidentate ligands and occupy mutually trans sites in a distorted monocapped square-antiprismatic geometry.http://scripts.iucr.org/cgi-bin/paper?S160053680905185X |
| spellingShingle | Qunbo Mei Bihai Tong (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(dibenzoylmethanido-κ2O,O′)bis(nitrato-κ2O,O′)neodymium(III) acetonitrile solvate Acta Crystallographica Section E |
| title | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(dibenzoylmethanido-κ2O,O′)bis(nitrato-κ2O,O′)neodymium(III) acetonitrile solvate |
| title_full | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(dibenzoylmethanido-κ2O,O′)bis(nitrato-κ2O,O′)neodymium(III) acetonitrile solvate |
| title_fullStr | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(dibenzoylmethanido-κ2O,O′)bis(nitrato-κ2O,O′)neodymium(III) acetonitrile solvate |
| title_full_unstemmed | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(dibenzoylmethanido-κ2O,O′)bis(nitrato-κ2O,O′)neodymium(III) acetonitrile solvate |
| title_short | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(dibenzoylmethanido-κ2O,O′)bis(nitrato-κ2O,O′)neodymium(III) acetonitrile solvate |
| title_sort | 4 amp 8242 allyloxy 2 2 amp 8242 6 amp 8242 2 amp 8242 amp 8242 terpyridine amp 954 3n n amp 8242 n amp 8242 amp 8242 dibenzoylmethanido amp 954 2o o amp 8242 bis nitrato amp 954 2o o amp 8242 neodymium iii acetonitrile solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680905185X |
| work_keys_str_mv | AT qunbomei 4amp8242allyloxy22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242dibenzoylmethanidoamp9542ooamp8242bisnitratoamp9542ooamp8242neodymiumiiiacetonitrilesolvate AT bihaitong 4amp8242allyloxy22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242dibenzoylmethanidoamp9542ooamp8242bisnitratoamp9542ooamp8242neodymiumiiiacetonitrilesolvate |