One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties
In order to synthesize the molecular magnetic material, the complex{Nd(hfac)3(NIT-5MeThien)}n(NIT-5MeThien=2-(5-Methyl-2ˊ-thienyl)-5--4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide) has been synthesized by the reaction using radical ligand and Nd(hfac)3•2H2O. X-ray diffraction analysis showed that t...
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| Format: | Article |
| Language: | English |
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EDP Sciences
2020-01-01
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| Series: | E3S Web of Conferences |
| Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/45/e3sconf_iceeb2020_04052.pdf |
| _version_ | 1818606235221491712 |
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| author | Dong Hui Yang Zhu Me |
| author_facet | Dong Hui Yang Zhu Me |
| author_sort | Dong Hui Yang |
| collection | DOAJ |
| description | In order to synthesize the molecular magnetic material, the complex{Nd(hfac)3(NIT-5MeThien)}n(NIT-5MeThien=2-(5-Methyl-2ˊ-thienyl)-5--4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide) has been synthesized by the reaction using radical ligand and Nd(hfac)3•2H2O. X-ray diffraction analysis showed that the compound belongs to the monoclinic system and constituted by Nd(hfac)3 and NIT-5MeThien to obtain a one-dimensional chain which nitroxide radical acted as a bridged ligand through the N-O groups. Variable temperature magnetization of complex was shown the antiferromagnetic interaction between Nd(III) ion and nitroxide radical. |
| first_indexed | 2024-12-16T14:07:38Z |
| format | Article |
| id | doaj.art-2bbd6ebeb74f41eab44e1ab309382452 |
| institution | Directory Open Access Journal |
| issn | 2267-1242 |
| language | English |
| last_indexed | 2024-12-16T14:07:38Z |
| publishDate | 2020-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | E3S Web of Conferences |
| spelling | doaj.art-2bbd6ebeb74f41eab44e1ab3093824522022-12-21T22:28:52ZengEDP SciencesE3S Web of Conferences2267-12422020-01-011850405210.1051/e3sconf/202018504052e3sconf_iceeb2020_04052One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic propertiesDong Hui YangZhu MeIn order to synthesize the molecular magnetic material, the complex{Nd(hfac)3(NIT-5MeThien)}n(NIT-5MeThien=2-(5-Methyl-2ˊ-thienyl)-5--4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide) has been synthesized by the reaction using radical ligand and Nd(hfac)3•2H2O. X-ray diffraction analysis showed that the compound belongs to the monoclinic system and constituted by Nd(hfac)3 and NIT-5MeThien to obtain a one-dimensional chain which nitroxide radical acted as a bridged ligand through the N-O groups. Variable temperature magnetization of complex was shown the antiferromagnetic interaction between Nd(III) ion and nitroxide radical.https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/45/e3sconf_iceeb2020_04052.pdf |
| spellingShingle | Dong Hui Yang Zhu Me One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties E3S Web of Conferences |
| title | One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties |
| title_full | One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties |
| title_fullStr | One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties |
| title_full_unstemmed | One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties |
| title_short | One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties |
| title_sort | one dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand structure and magnetic properties |
| url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/45/e3sconf_iceeb2020_04052.pdf |
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