Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)]

Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)]

In the title complex, [Y2(C5H6O4)3(C12H8N2)2]n, three glutarate groups and two 1,10-phenanthroline molecules surround the two YIII ions. Both YIII ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal&#821...

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Bibliographic Details
Main Authors: Ling Jin, Hong-lin Zhu
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811027188
Description
Summary:In the title complex, [Y2(C5H6O4)3(C12H8N2)2]n, three glutarate groups and two 1,10-phenanthroline molecules surround the two YIII ions. Both YIII ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal–prismatic geometry. The YIII ions are bridged by glutarate ligands in three modes, forming a layered, polymeric structure. The resulting layers are assembled by π–π stacking interactions [centroid–centroid distances = 3.740 (3) and 3.571 (3) Å] into a three-dimensional supramolecular architecture.
ISSN:1600-5368

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