Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)]
In the title complex, [Y2(C5H6O4)3(C12H8N2)2]n, three glutarate groups and two 1,10-phenanthroline molecules surround the two YIII ions. Both YIII ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal&#821...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811027188 |
| _version_ | 1798031660840648704 |
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| author | Ling Jin Hong-lin Zhu |
| author_facet | Ling Jin Hong-lin Zhu |
| author_sort | Ling Jin |
| collection | DOAJ |
| description | In the title complex, [Y2(C5H6O4)3(C12H8N2)2]n, three glutarate groups and two 1,10-phenanthroline molecules surround the two YIII ions. Both YIII ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal–prismatic geometry. The YIII ions are bridged by glutarate ligands in three modes, forming a layered, polymeric structure. The resulting layers are assembled by π–π stacking interactions [centroid–centroid distances = 3.740 (3) and 3.571 (3) Å] into a three-dimensional supramolecular architecture. |
| first_indexed | 2024-04-11T20:00:00Z |
| format | Article |
| id | doaj.art-2bbd930d0a8342d2ae96a77d9cd4b907 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T20:00:00Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2bbd930d0a8342d2ae96a77d9cd4b9072022-12-22T04:05:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1088m108810.1107/S1600536811027188Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)]Ling JinHong-lin ZhuIn the title complex, [Y2(C5H6O4)3(C12H8N2)2]n, three glutarate groups and two 1,10-phenanthroline molecules surround the two YIII ions. Both YIII ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal–prismatic geometry. The YIII ions are bridged by glutarate ligands in three modes, forming a layered, polymeric structure. The resulting layers are assembled by π–π stacking interactions [centroid–centroid distances = 3.740 (3) and 3.571 (3) Å] into a three-dimensional supramolecular architecture.http://scripts.iucr.org/cgi-bin/paper?S1600536811027188 |
| spellingShingle | Ling Jin Hong-lin Zhu Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)] Acta Crystallographica Section E |
| title | Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
| title_full | Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
| title_fullStr | Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
| title_full_unstemmed | Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
| title_short | Poly[μ4-glutarato-di-μ3-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
| title_sort | poly amp 956 4 glutarato di amp 956 3 glutarato bis 1 10 phenanthroline diyttrium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811027188 |
| work_keys_str_mv | AT lingjin polyamp9564glutaratodiamp9563glutaratobis110phenanthrolinediyttriumiii AT honglinzhu polyamp9564glutaratodiamp9563glutaratobis110phenanthrolinediyttriumiii |