Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)

In the title complex, [Co(NCS)2(C10H9N3O)2(H2O)2], the CoII ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octahedral CoN4O2 coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the cryst...

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Main Author: Zhong Nian Yang
Format: Article
Language:English
Published: International Union of Crystallography 2008-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808030882
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author Zhong Nian Yang
author_facet Zhong Nian Yang
author_sort Zhong Nian Yang
collection DOAJ
description In the title complex, [Co(NCS)2(C10H9N3O)2(H2O)2], the CoII ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octahedral CoN4O2 coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, intermolecular O—H...N and O—H...S hydrogen bonds link complex molecules into a three-dimensional network.
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spelling doaj.art-2c0a77b7b18e4eebac34ee3990b108e92022-12-21T19:49:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1350m135010.1107/S1600536808030882Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)Zhong Nian YangIn the title complex, [Co(NCS)2(C10H9N3O)2(H2O)2], the CoII ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octahedral CoN4O2 coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, intermolecular O—H...N and O—H...S hydrogen bonds link complex molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808030882
spellingShingle Zhong Nian Yang
Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)
Acta Crystallographica Section E
title Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)
title_full Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)
title_fullStr Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)
title_full_unstemmed Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)
title_short Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)
title_sort diaquabis 2 2 pyridylmethoxy pyrazine 954 n4 bis thiocyanato 954 n cobalt ii
url http://scripts.iucr.org/cgi-bin/paper?S1600536808030882
work_keys_str_mv AT zhongnianyang diaquabis22pyridylmethoxypyrazine954n4bisthiocyanato954ncobaltii