Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)
In the title complex, [Co(NCS)2(C10H9N3O)2(H2O)2], the CoII ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octahedral CoN4O2 coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the cryst...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2008-10-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808030882 |
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author | Zhong Nian Yang |
author_facet | Zhong Nian Yang |
author_sort | Zhong Nian Yang |
collection | DOAJ |
description | In the title complex, [Co(NCS)2(C10H9N3O)2(H2O)2], the CoII ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octahedral CoN4O2 coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, intermolecular O—H...N and O—H...S hydrogen bonds link complex molecules into a three-dimensional network. |
first_indexed | 2024-12-20T06:53:12Z |
format | Article |
id | doaj.art-2c0a77b7b18e4eebac34ee3990b108e9 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-20T06:53:12Z |
publishDate | 2008-10-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-2c0a77b7b18e4eebac34ee3990b108e92022-12-21T19:49:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1350m135010.1107/S1600536808030882Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II)Zhong Nian YangIn the title complex, [Co(NCS)2(C10H9N3O)2(H2O)2], the CoII ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octahedral CoN4O2 coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, intermolecular O—H...N and O—H...S hydrogen bonds link complex molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808030882 |
spellingShingle | Zhong Nian Yang Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II) Acta Crystallographica Section E |
title | Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II) |
title_full | Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II) |
title_fullStr | Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II) |
title_full_unstemmed | Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II) |
title_short | Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN4]bis(thiocyanato-κN)cobalt(II) |
title_sort | diaquabis 2 2 pyridylmethoxy pyrazine 954 n4 bis thiocyanato 954 n cobalt ii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536808030882 |
work_keys_str_mv | AT zhongnianyang diaquabis22pyridylmethoxypyrazine954n4bisthiocyanato954ncobaltii |