Characterization of Hydrogen Bonds by IR Spectroscopy
In the identification and quantification of hydrogen bond, as one of the most abundant non-covalent interactions in phenomena like self-assembly and molecular recognition, IR spectrosopy has been employed as the most sensitive method. The performance of the high dilution method enables determination...
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| Format: | Article |
| Language: | English |
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Croatian Society of Chemical Engineers
2012-05-01
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| Series: | Kemija u Industriji |
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| Online Access: | http://pierre.fkit.hr/hdki/kui/vol61/broj5-6/289.pdf |
| _version_ | 1818212841232007168 |
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| author | Vojta, D. |
| author_facet | Vojta, D. |
| author_sort | Vojta, D. |
| collection | DOAJ |
| description | In the identification and quantification of hydrogen bond, as one of the most abundant non-covalent interactions in phenomena like self-assembly and molecular recognition, IR spectrosopy has been employed as the most sensitive method. The performance of the high dilution method enables determination of the stability constant of hydrogen-bonded complex as one of the most important thermodynamic quantities used in their characterization. However, the alleged experimental simplicity of the mentioned method is loaded with errors originating not only from researcher intervention but also independent from it. The second source of error is particularly emphasized and elaborated in this paper, which is designed as the recipe for the successful characterization of hydrogen bonds. Besides the enumeration of all steps in the determination of hydrogen-bonded stability constants, the reader can be acquainted with the most important ex perimental conditions that should be fulfilled in order to minimize the naturally occurring errors in this type of investigation. In the spectral analysis, the application of both uni- and multivariate approach has been discussed. Some computer packages, considering the latter, are mentioned, described, and recommended. KUI -10/2012Received August 1, 2011Accepted October 24, 2011 |
| first_indexed | 2024-12-12T05:54:48Z |
| format | Article |
| id | doaj.art-2c17634e86944e7d96db35a5f3bb93b2 |
| institution | Directory Open Access Journal |
| issn | 0022-9830 1334-9090 |
| language | English |
| last_indexed | 2024-12-12T05:54:48Z |
| publishDate | 2012-05-01 |
| publisher | Croatian Society of Chemical Engineers |
| record_format | Article |
| series | Kemija u Industriji |
| spelling | doaj.art-2c17634e86944e7d96db35a5f3bb93b22022-12-22T00:35:35ZengCroatian Society of Chemical EngineersKemija u Industriji0022-98301334-90902012-05-016105-06289294Characterization of Hydrogen Bonds by IR SpectroscopyVojta, D.In the identification and quantification of hydrogen bond, as one of the most abundant non-covalent interactions in phenomena like self-assembly and molecular recognition, IR spectrosopy has been employed as the most sensitive method. The performance of the high dilution method enables determination of the stability constant of hydrogen-bonded complex as one of the most important thermodynamic quantities used in their characterization. However, the alleged experimental simplicity of the mentioned method is loaded with errors originating not only from researcher intervention but also independent from it. The second source of error is particularly emphasized and elaborated in this paper, which is designed as the recipe for the successful characterization of hydrogen bonds. Besides the enumeration of all steps in the determination of hydrogen-bonded stability constants, the reader can be acquainted with the most important ex perimental conditions that should be fulfilled in order to minimize the naturally occurring errors in this type of investigation. In the spectral analysis, the application of both uni- and multivariate approach has been discussed. Some computer packages, considering the latter, are mentioned, described, and recommended. KUI -10/2012Received August 1, 2011Accepted October 24, 2011http://pierre.fkit.hr/hdki/kui/vol61/broj5-6/289.pdfHydrogen BondsIR Spectroscopy |
| spellingShingle | Vojta, D. Characterization of Hydrogen Bonds by IR Spectroscopy Kemija u Industriji Hydrogen Bonds IR Spectroscopy |
| title | Characterization of Hydrogen Bonds by IR Spectroscopy |
| title_full | Characterization of Hydrogen Bonds by IR Spectroscopy |
| title_fullStr | Characterization of Hydrogen Bonds by IR Spectroscopy |
| title_full_unstemmed | Characterization of Hydrogen Bonds by IR Spectroscopy |
| title_short | Characterization of Hydrogen Bonds by IR Spectroscopy |
| title_sort | characterization of hydrogen bonds by ir spectroscopy |
| topic | Hydrogen Bonds IR Spectroscopy |
| url | http://pierre.fkit.hr/hdki/kui/vol61/broj5-6/289.pdf |
| work_keys_str_mv | AT vojtad characterizationofhydrogenbondsbyirspectroscopy |