Seed-aided green synthesis of metal-organic frameworks in water
Green synthesis of metal-organic frameworks (MOFs) in water with alleviated environmental influence and reduced cost is an essential step to transfer laboratory MOFs research to industrial application. Switching from the commonly used organic solvents to pure water encounters challenges of the poor...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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KeAi Communications Co. Ltd.
2023-03-01
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| Series: | Green Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666952822000322 |
| _version_ | 1811167224398872576 |
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| author | Hao-Tian An Xin Zhang Chen Dong Mu-Yao Lu Rui Li Yabo Xie Lin-Hua Xie Jian-Rong Li |
| author_facet | Hao-Tian An Xin Zhang Chen Dong Mu-Yao Lu Rui Li Yabo Xie Lin-Hua Xie Jian-Rong Li |
| author_sort | Hao-Tian An |
| collection | DOAJ |
| description | Green synthesis of metal-organic frameworks (MOFs) in water with alleviated environmental influence and reduced cost is an essential step to transfer laboratory MOFs research to industrial application. Switching from the commonly used organic solvents to pure water encounters challenges of the poor solubility of organic linkers, slow reaction kinetics, and the formation of polymorphic products. So far, a universal MOFs synthetic strategy in water system has yet to be developed. This study reports the seed-aided synthesis of eleven MOFs with diverse compositions and structures while pure water serving as solvent. The corresponding reaction temperature and time of using this new strategy were reduced compared with original synthetic approaches, while the products maintain porous structure and high crystallinity. The success of this strategy relies on the addition of parent MOFs as seeds which could promote crystallization process by skipping the time-consuming induction period and avoiding the formation of polymorphic impurities. |
| first_indexed | 2024-04-10T16:06:48Z |
| format | Article |
| id | doaj.art-2c18a96871ed4ab98bce838d8cc8731d |
| institution | Directory Open Access Journal |
| issn | 2666-9528 |
| language | English |
| last_indexed | 2024-04-10T16:06:48Z |
| publishDate | 2023-03-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Chemical Engineering |
| spelling | doaj.art-2c18a96871ed4ab98bce838d8cc8731d2023-02-10T04:23:32ZengKeAi Communications Co. Ltd.Green Chemical Engineering2666-95282023-03-01416472Seed-aided green synthesis of metal-organic frameworks in waterHao-Tian An0Xin Zhang1Chen Dong2Mu-Yao Lu3Rui Li4Yabo Xie5Lin-Hua Xie6Jian-Rong Li7Beijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, ChinaBeijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, ChinaBeijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, ChinaBeijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, ChinaBeijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, ChinaBeijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, ChinaBeijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, ChinaCorresponding author.; Beijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, ChinaGreen synthesis of metal-organic frameworks (MOFs) in water with alleviated environmental influence and reduced cost is an essential step to transfer laboratory MOFs research to industrial application. Switching from the commonly used organic solvents to pure water encounters challenges of the poor solubility of organic linkers, slow reaction kinetics, and the formation of polymorphic products. So far, a universal MOFs synthetic strategy in water system has yet to be developed. This study reports the seed-aided synthesis of eleven MOFs with diverse compositions and structures while pure water serving as solvent. The corresponding reaction temperature and time of using this new strategy were reduced compared with original synthetic approaches, while the products maintain porous structure and high crystallinity. The success of this strategy relies on the addition of parent MOFs as seeds which could promote crystallization process by skipping the time-consuming induction period and avoiding the formation of polymorphic impurities.http://www.sciencedirect.com/science/article/pii/S2666952822000322Metal-organic frameworksCarbon neutralityCoal bed methaneGreenhouse gasFossil fuel |
| spellingShingle | Hao-Tian An Xin Zhang Chen Dong Mu-Yao Lu Rui Li Yabo Xie Lin-Hua Xie Jian-Rong Li Seed-aided green synthesis of metal-organic frameworks in water Green Chemical Engineering Metal-organic frameworks Carbon neutrality Coal bed methane Greenhouse gas Fossil fuel |
| title | Seed-aided green synthesis of metal-organic frameworks in water |
| title_full | Seed-aided green synthesis of metal-organic frameworks in water |
| title_fullStr | Seed-aided green synthesis of metal-organic frameworks in water |
| title_full_unstemmed | Seed-aided green synthesis of metal-organic frameworks in water |
| title_short | Seed-aided green synthesis of metal-organic frameworks in water |
| title_sort | seed aided green synthesis of metal organic frameworks in water |
| topic | Metal-organic frameworks Carbon neutrality Coal bed methane Greenhouse gas Fossil fuel |
| url | http://www.sciencedirect.com/science/article/pii/S2666952822000322 |
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