[Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate

[Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate

The title compound, [Fe2Ti(C5H5)4)(C10H8O2P2S4)]·3C4H8O, contains a central seven-membered TiO2P2S2 ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti—O distance being marginally longer for the anisyl deri...

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Bibliographic Details
Main Authors: Mehmet Karakus, J. Derek Woollins, Peter Lönnecke, Evamarie Hey-Hawkins
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812010811
Description
Summary:The title compound, [Fe2Ti(C5H5)4)(C10H8O2P2S4)]·3C4H8O, contains a central seven-membered TiO2P2S2 ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti—O distance being marginally longer for the anisyl derivative. Two tetrahydrofuran solvent molecules are each disordered on a twofold axis.
ISSN:1600-5368

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