[Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate
The title compound, [Fe2Ti(C5H5)4)(C10H8O2P2S4)]·3C4H8O, contains a central seven-membered TiO2P2S2 ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti—O distance being marginally longer for the anisyl deri...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812010811 |
| _version_ | 1828129150562467840 |
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| author | Mehmet Karakus J. Derek Woollins Peter Lönnecke Evamarie Hey-Hawkins |
| author_facet | Mehmet Karakus J. Derek Woollins Peter Lönnecke Evamarie Hey-Hawkins |
| author_sort | Mehmet Karakus |
| collection | DOAJ |
| description | The title compound, [Fe2Ti(C5H5)4)(C10H8O2P2S4)]·3C4H8O, contains a central seven-membered TiO2P2S2 ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti—O distance being marginally longer for the anisyl derivative. Two tetrahydrofuran solvent molecules are each disordered on a twofold axis. |
| first_indexed | 2024-04-11T16:15:11Z |
| format | Article |
| id | doaj.art-2c68d250c0a146b093019cf0634d5ab9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:15:11Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2c68d250c0a146b093019cf0634d5ab92022-12-22T04:14:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m428m42810.1107/S1600536812010811[Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvateMehmet KarakusJ. Derek WoollinsPeter LönneckeEvamarie Hey-HawkinsThe title compound, [Fe2Ti(C5H5)4)(C10H8O2P2S4)]·3C4H8O, contains a central seven-membered TiO2P2S2 ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti—O distance being marginally longer for the anisyl derivative. Two tetrahydrofuran solvent molecules are each disordered on a twofold axis.http://scripts.iucr.org/cgi-bin/paper?S1600536812010811 |
| spellingShingle | Mehmet Karakus J. Derek Woollins Peter Lönnecke Evamarie Hey-Hawkins [Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate Acta Crystallographica Section E |
| title | [Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate |
| title_full | [Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate |
| title_fullStr | [Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate |
| title_full_unstemmed | [Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate |
| title_short | [Disulfanediylbis(ferrocenylthiophosphinato)-κ2O,O]titanocene tetrahydrofuran trisolvate |
| title_sort | disulfanediylbis ferrocenylthiophosphinato amp 954 2o o titanocene tetrahydrofuran trisolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812010811 |
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