Gold-catalyzed ethylene cyclopropanation
Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBArF4 (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene; BArF4 = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2019-01-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.15.7 |
| _version_ | 1818655368109096960 |
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| author | Silvia G. Rull Andrea Olmos Pedro J. Pérez |
| author_facet | Silvia G. Rull Andrea Olmos Pedro J. Pérez |
| author_sort | Silvia G. Rull |
| collection | DOAJ |
| description | Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBArF4 (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene; BArF4 = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate). |
| first_indexed | 2024-12-17T03:08:34Z |
| format | Article |
| id | doaj.art-2c7ef6e0fd8649bba1a2ba1323c55a43 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-17T03:08:34Z |
| publishDate | 2019-01-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-2c7ef6e0fd8649bba1a2ba1323c55a432022-12-21T22:05:53ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972019-01-01151677110.3762/bjoc.15.71860-5397-15-7Gold-catalyzed ethylene cyclopropanationSilvia G. Rull0Andrea Olmos1Pedro J. Pérez2Laboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química, Universidad de Huelva, Campus de El Carmen 21007 Huelva, SpainLaboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química, Universidad de Huelva, Campus de El Carmen 21007 Huelva, SpainLaboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química, Universidad de Huelva, Campus de El Carmen 21007 Huelva, SpainEthylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N2CHCO2Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBArF4 (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene; BArF4 = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).https://doi.org/10.3762/bjoc.15.7carbene transfercyclopropanecyclopropylcarboxylateethylene cyclopropanationethyl diazoacetategold catalysis |
| spellingShingle | Silvia G. Rull Andrea Olmos Pedro J. Pérez Gold-catalyzed ethylene cyclopropanation Beilstein Journal of Organic Chemistry carbene transfer cyclopropane cyclopropylcarboxylate ethylene cyclopropanation ethyl diazoacetate gold catalysis |
| title | Gold-catalyzed ethylene cyclopropanation |
| title_full | Gold-catalyzed ethylene cyclopropanation |
| title_fullStr | Gold-catalyzed ethylene cyclopropanation |
| title_full_unstemmed | Gold-catalyzed ethylene cyclopropanation |
| title_short | Gold-catalyzed ethylene cyclopropanation |
| title_sort | gold catalyzed ethylene cyclopropanation |
| topic | carbene transfer cyclopropane cyclopropylcarboxylate ethylene cyclopropanation ethyl diazoacetate gold catalysis |
| url | https://doi.org/10.3762/bjoc.15.7 |
| work_keys_str_mv | AT silviagrull goldcatalyzedethylenecyclopropanation AT andreaolmos goldcatalyzedethylenecyclopropanation AT pedrojperez goldcatalyzedethylenecyclopropanation |