The Procedure for Evaluating the Adsorption Energy Distribution from an Analysis of Thermodesorption Spectra Based on the Statistical Rate Theory

We have recently proposed a new method for evaluating the adsorption energy distribution function χ(ε) from the numerical analysis of thermodesorption spectra. This method is based on an application of the Statistical Rate Theory developed by Ward et al . (1982). In this paper, we present some simpl...

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Main Authors: Tomasz Panczyk, Wladyslaw Rudzinski, Tadeusz Borowiecki, Anna Dominko
Format: Article
Language:English
Published: SAGE Publications 2002-05-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/02636170260295560
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author Tomasz Panczyk
Wladyslaw Rudzinski
Tadeusz Borowiecki
Anna Dominko
author_facet Tomasz Panczyk
Wladyslaw Rudzinski
Tadeusz Borowiecki
Anna Dominko
author_sort Tomasz Panczyk
collection DOAJ
description We have recently proposed a new method for evaluating the adsorption energy distribution function χ(ε) from the numerical analysis of thermodesorption spectra. This method is based on an application of the Statistical Rate Theory developed by Ward et al . (1982). In this paper, we present some simplifications of this method thereby allowing its ready application. Illustrative calculations for the nitrogen thermodesorption spectra from the surface of molecular sieve carbon fibres (MSCF) are presented.
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spelling doaj.art-2c887c4f87244e329abb66e67b7cc07d2024-03-02T16:05:11ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382002-05-012010.1260/02636170260295560The Procedure for Evaluating the Adsorption Energy Distribution from an Analysis of Thermodesorption Spectra Based on the Statistical Rate TheoryTomasz Panczyk0Wladyslaw Rudzinski1Tadeusz Borowiecki2Anna Dominko3 Department of Theoretical Chemistry, Faculty of Chemistry, Maria Curie-Sklodowska University, pl. M. Curie-Sklodowskiej 3, 20-031 Lublin, Poland Department of Theoretical Chemistry, Faculty of Chemistry, Maria Curie-Sklodowska University, pl. M. Curie-Sklodowskiej 3, 20-031 Lublin, Poland Department of Chemical Technology, Faculty of Chemistry, Maria Curie-Sklodowska University, pl. M. Curie-Sklodowskiej 3, 20-031 Lublin, Poland Department of Chemical Technology, Faculty of Chemistry, Maria Curie-Sklodowska University, pl. M. Curie-Sklodowskiej 3, 20-031 Lublin, PolandWe have recently proposed a new method for evaluating the adsorption energy distribution function χ(ε) from the numerical analysis of thermodesorption spectra. This method is based on an application of the Statistical Rate Theory developed by Ward et al . (1982). In this paper, we present some simplifications of this method thereby allowing its ready application. Illustrative calculations for the nitrogen thermodesorption spectra from the surface of molecular sieve carbon fibres (MSCF) are presented.https://doi.org/10.1260/02636170260295560
spellingShingle Tomasz Panczyk
Wladyslaw Rudzinski
Tadeusz Borowiecki
Anna Dominko
The Procedure for Evaluating the Adsorption Energy Distribution from an Analysis of Thermodesorption Spectra Based on the Statistical Rate Theory
Adsorption Science & Technology
title The Procedure for Evaluating the Adsorption Energy Distribution from an Analysis of Thermodesorption Spectra Based on the Statistical Rate Theory
title_full The Procedure for Evaluating the Adsorption Energy Distribution from an Analysis of Thermodesorption Spectra Based on the Statistical Rate Theory
title_fullStr The Procedure for Evaluating the Adsorption Energy Distribution from an Analysis of Thermodesorption Spectra Based on the Statistical Rate Theory
title_full_unstemmed The Procedure for Evaluating the Adsorption Energy Distribution from an Analysis of Thermodesorption Spectra Based on the Statistical Rate Theory
title_short The Procedure for Evaluating the Adsorption Energy Distribution from an Analysis of Thermodesorption Spectra Based on the Statistical Rate Theory
title_sort procedure for evaluating the adsorption energy distribution from an analysis of thermodesorption spectra based on the statistical rate theory
url https://doi.org/10.1260/02636170260295560
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