Magnetically Induced Anisotropic Interaction in Colloidal Assembly

The wide accessibility to nanostructures with high uniformity and controllable sizes and morphologies provides great opportunities for creating complex superstructures with unique functionalities. Employing anisotropic nanostructures as the building blocks significantly enriches the superstructural...

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Main Authors: Qingsong Fan, Zhiwei Li, Chaolumen Wu, Yadong Yin
Format: Article
Language:English
Published: American Chemical Society 2023-06-01
Series:Precision Chemistry
Online Access:https://doi.org/10.1021/prechem.3c00012
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author Qingsong Fan
Zhiwei Li
Chaolumen Wu
Yadong Yin
author_facet Qingsong Fan
Zhiwei Li
Chaolumen Wu
Yadong Yin
author_sort Qingsong Fan
collection DOAJ
description The wide accessibility to nanostructures with high uniformity and controllable sizes and morphologies provides great opportunities for creating complex superstructures with unique functionalities. Employing anisotropic nanostructures as the building blocks significantly enriches the superstructural phases, while their orientational control for obtaining long-range orders has remained a significant challenge. One solution is to introduce magnetic components into the anisotropic nanostructures to enable precise control of their orientations and positions in the superstructures by manipulating magnetic interactions. Recognizing the importance of magnetic anisotropy in colloidal assembly, we provide here an overview of magnetic field-guided self-assembly of magnetic nanoparticles with typical anisotropic shapes, including rods, cubes, plates, and peanuts. The Review starts with discussing the magnetic energy of nanoparticles, appreciating the vital roles of magneto-crystalline and shape anisotropies in determining the easy magnetization direction of the anisotropic nanostructures. It then introduces superstructures assembled from various magnetic building blocks and summarizes their unique properties and intriguing applications. It concludes with a discussion of remaining challenges and an outlook of future research opportunities that the magnetic assembly strategy may offer for colloidal assembly.
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spelling doaj.art-2c94c48de81242a0bddefb610144d98e2023-08-21T18:03:01ZengAmerican Chemical SocietyPrecision Chemistry2771-93162023-06-011527229810.1021/prechem.3c00012Magnetically Induced Anisotropic Interaction in Colloidal AssemblyQingsong FanZhiwei LiChaolumen WuYadong YinThe wide accessibility to nanostructures with high uniformity and controllable sizes and morphologies provides great opportunities for creating complex superstructures with unique functionalities. Employing anisotropic nanostructures as the building blocks significantly enriches the superstructural phases, while their orientational control for obtaining long-range orders has remained a significant challenge. One solution is to introduce magnetic components into the anisotropic nanostructures to enable precise control of their orientations and positions in the superstructures by manipulating magnetic interactions. Recognizing the importance of magnetic anisotropy in colloidal assembly, we provide here an overview of magnetic field-guided self-assembly of magnetic nanoparticles with typical anisotropic shapes, including rods, cubes, plates, and peanuts. The Review starts with discussing the magnetic energy of nanoparticles, appreciating the vital roles of magneto-crystalline and shape anisotropies in determining the easy magnetization direction of the anisotropic nanostructures. It then introduces superstructures assembled from various magnetic building blocks and summarizes their unique properties and intriguing applications. It concludes with a discussion of remaining challenges and an outlook of future research opportunities that the magnetic assembly strategy may offer for colloidal assembly.https://doi.org/10.1021/prechem.3c00012
spellingShingle Qingsong Fan
Zhiwei Li
Chaolumen Wu
Yadong Yin
Magnetically Induced Anisotropic Interaction in Colloidal Assembly
Precision Chemistry
title Magnetically Induced Anisotropic Interaction in Colloidal Assembly
title_full Magnetically Induced Anisotropic Interaction in Colloidal Assembly
title_fullStr Magnetically Induced Anisotropic Interaction in Colloidal Assembly
title_full_unstemmed Magnetically Induced Anisotropic Interaction in Colloidal Assembly
title_short Magnetically Induced Anisotropic Interaction in Colloidal Assembly
title_sort magnetically induced anisotropic interaction in colloidal assembly
url https://doi.org/10.1021/prechem.3c00012
work_keys_str_mv AT qingsongfan magneticallyinducedanisotropicinteractionincolloidalassembly
AT zhiweili magneticallyinducedanisotropicinteractionincolloidalassembly
AT chaolumenwu magneticallyinducedanisotropicinteractionincolloidalassembly
AT yadongyin magneticallyinducedanisotropicinteractionincolloidalassembly