Geochemical assessment of platinum group metals for phytomining

Abstract Phytomining is suggested as a technology to obtain platinum group metals (PGMs) nanoparticles from plants grown on the mineralized soils or tailings. Samples from North American Palladium (Canada) and gossans from Broken Hill (BH) (Australia) were studied to assess the possibility of using...

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Main Authors: Peipei Shi, Marcello Veiga, Christopher Anderson
Format: Article
Language:English
Published: Fundação Gorceix 2019-12-01
Series:REM: International Engineering Journal
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S2448-167X2020000100085&tlng=en
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author Peipei Shi
Marcello Veiga
Christopher Anderson
author_facet Peipei Shi
Marcello Veiga
Christopher Anderson
author_sort Peipei Shi
collection DOAJ
description Abstract Phytomining is suggested as a technology to obtain platinum group metals (PGMs) nanoparticles from plants grown on the mineralized soils or tailings. Samples from North American Palladium (Canada) and gossans from Broken Hill (BH) (Australia) were studied to assess the possibility of using these PGM-rich samples as substrates for phytomining. The bioavailability of PGMs was indirectly assessed using geochemical procedures. The selective extractions showed that the highest available concentration of Pd is 5.38 ppm in BH gossan 1. The extraction of PGMs by ammonium acetate, fulvic acid or citrate-dithionite indicates natural availability to plants. The BH gossan 1 was the best of the five studied samples for phytomining of Pd due to available Pd concentration (> 2 mg/kg), low Electric Conductivity (< 2dS/m), high CEC (Cation Exchange Capacity) (38.8 meq/100g), and proper pH (6.5). Cu-tolerant plant species should be chosen to grow on BH gossan 1. A criterium for choosing substrates for phytomining of Pd was developed comprising various classical soil parameters plus selective extraction procedures.
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spelling doaj.art-2c9caea30d1943038267127c7f0537292022-12-22T04:13:39ZengFundação GorceixREM: International Engineering Journal2448-167X2019-12-01731859110.1590/0370-44672019730038Geochemical assessment of platinum group metals for phytominingPeipei Shihttps://orcid.org/0000-0003-3399-0154Marcello Veigahttps://orcid.org/0000-0001-9261-738XChristopher Andersonhttps://orcid.org/0000-0003-0935-1475Abstract Phytomining is suggested as a technology to obtain platinum group metals (PGMs) nanoparticles from plants grown on the mineralized soils or tailings. Samples from North American Palladium (Canada) and gossans from Broken Hill (BH) (Australia) were studied to assess the possibility of using these PGM-rich samples as substrates for phytomining. The bioavailability of PGMs was indirectly assessed using geochemical procedures. The selective extractions showed that the highest available concentration of Pd is 5.38 ppm in BH gossan 1. The extraction of PGMs by ammonium acetate, fulvic acid or citrate-dithionite indicates natural availability to plants. The BH gossan 1 was the best of the five studied samples for phytomining of Pd due to available Pd concentration (> 2 mg/kg), low Electric Conductivity (< 2dS/m), high CEC (Cation Exchange Capacity) (38.8 meq/100g), and proper pH (6.5). Cu-tolerant plant species should be chosen to grow on BH gossan 1. A criterium for choosing substrates for phytomining of Pd was developed comprising various classical soil parameters plus selective extraction procedures.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S2448-167X2020000100085&tlng=enphytominingplatinum group metalsbioavailabilityplant growth parameters
spellingShingle Peipei Shi
Marcello Veiga
Christopher Anderson
Geochemical assessment of platinum group metals for phytomining
REM: International Engineering Journal
phytomining
platinum group metals
bioavailability
plant growth parameters
title Geochemical assessment of platinum group metals for phytomining
title_full Geochemical assessment of platinum group metals for phytomining
title_fullStr Geochemical assessment of platinum group metals for phytomining
title_full_unstemmed Geochemical assessment of platinum group metals for phytomining
title_short Geochemical assessment of platinum group metals for phytomining
title_sort geochemical assessment of platinum group metals for phytomining
topic phytomining
platinum group metals
bioavailability
plant growth parameters
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S2448-167X2020000100085&tlng=en
work_keys_str_mv AT peipeishi geochemicalassessmentofplatinumgroupmetalsforphytomining
AT marcelloveiga geochemicalassessmentofplatinumgroupmetalsforphytomining
AT christopheranderson geochemicalassessmentofplatinumgroupmetalsforphytomining