Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging

In order to study the cross-linking density and aging constitutive relationship of HTPB coating during storage, the thermal accelerated aging tests at 0%, 3%, 6% and 9% prestrains were carried out. The cross-linking density of HTPB coating at different aging stages were tested using low-field 1H NMR...

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Main Authors: Yong-qiang Du, Jian Zheng, Chao Xiong
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2020-04-01
Series:Defence Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214914719304805
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author Yong-qiang Du
Jian Zheng
Chao Xiong
author_facet Yong-qiang Du
Jian Zheng
Chao Xiong
author_sort Yong-qiang Du
collection DOAJ
description In order to study the cross-linking density and aging constitutive relationship of HTPB coating during storage, the thermal accelerated aging tests at 0%, 3%, 6% and 9% prestrains were carried out. The cross-linking density of HTPB coating at different aging stages were tested using low-field 1H NMR and the variation of cross-linking density was analyzed. The aging model of cross-linking density considering the chemical aging and the physical stretching factors was established. The uniaxial tensile tests were carried out on HTPB coating at different aging stages and the cross-linking density was introduced into Ogden hyperelastic constitutive model as a characterization parameter of correction coefficient. Combined with uniaxial tensile test results, a prestrain aging constitutive model of HTPB coating was established. The results show that the cross-linking density of HTPB coating increases rapidly at first and then slowly with the increase of thermal accelerated aging time without prestrain. Under prestrain conditions, the cross-linking density of HTPB coating decreases at the early stage, and increases rapidly at first and then slowly at the middle and late stages of thermal accelerated aging. The correlation coefficients of aging model of cross-linking density and aging constitutive model with test results are R > 0.9500 and R > 0.9900 respectively, which can be used to accurately describe the cross-linking density and aging constitutive relationship of HTPB coating under prestrain accelerated thermal aging conditions.
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spelling doaj.art-2cd24baaebce4c14a239e83409da7a6e2022-12-21T18:35:32ZengKeAi Communications Co., Ltd.Defence Technology2214-91472020-04-01162439446Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated agingYong-qiang Du0Jian Zheng1Chao Xiong2Shijiazhuang Campus, Army Engineering University, Shijiazhuang 050003, ChinaCorresponding author.; Shijiazhuang Campus, Army Engineering University, Shijiazhuang 050003, ChinaShijiazhuang Campus, Army Engineering University, Shijiazhuang 050003, ChinaIn order to study the cross-linking density and aging constitutive relationship of HTPB coating during storage, the thermal accelerated aging tests at 0%, 3%, 6% and 9% prestrains were carried out. The cross-linking density of HTPB coating at different aging stages were tested using low-field 1H NMR and the variation of cross-linking density was analyzed. The aging model of cross-linking density considering the chemical aging and the physical stretching factors was established. The uniaxial tensile tests were carried out on HTPB coating at different aging stages and the cross-linking density was introduced into Ogden hyperelastic constitutive model as a characterization parameter of correction coefficient. Combined with uniaxial tensile test results, a prestrain aging constitutive model of HTPB coating was established. The results show that the cross-linking density of HTPB coating increases rapidly at first and then slowly with the increase of thermal accelerated aging time without prestrain. Under prestrain conditions, the cross-linking density of HTPB coating decreases at the early stage, and increases rapidly at first and then slowly at the middle and late stages of thermal accelerated aging. The correlation coefficients of aging model of cross-linking density and aging constitutive model with test results are R > 0.9500 and R > 0.9900 respectively, which can be used to accurately describe the cross-linking density and aging constitutive relationship of HTPB coating under prestrain accelerated thermal aging conditions.http://www.sciencedirect.com/science/article/pii/S2214914719304805Prestrain thermal accelerated agingLow-field 1H NMRCross-linking densityAging constitutive model
spellingShingle Yong-qiang Du
Jian Zheng
Chao Xiong
Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging
Defence Technology
Prestrain thermal accelerated aging
Low-field 1H NMR
Cross-linking density
Aging constitutive model
title Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging
title_full Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging
title_fullStr Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging
title_full_unstemmed Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging
title_short Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging
title_sort cross linking density and aging constitutive model of htpb coating under prestrain thermal accelerated aging
topic Prestrain thermal accelerated aging
Low-field 1H NMR
Cross-linking density
Aging constitutive model
url http://www.sciencedirect.com/science/article/pii/S2214914719304805
work_keys_str_mv AT yongqiangdu crosslinkingdensityandagingconstitutivemodelofhtpbcoatingunderprestrainthermalacceleratedaging
AT jianzheng crosslinkingdensityandagingconstitutivemodelofhtpbcoatingunderprestrainthermalacceleratedaging
AT chaoxiong crosslinkingdensityandagingconstitutivemodelofhtpbcoatingunderprestrainthermalacceleratedaging