The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes
Dithiocarbamate complexes are of immense interest due to their diverse structural properties and extensive application in various areas. They possess two sulfur atoms that often act as the binding sites for metal coordination in a monodentate, bidentate, or anisodentate fashion. These different coor...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2021-09-01
|
| Series: | Open Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/chem-2021-0080 |
| _version_ | 1818322805900443648 |
|---|---|
| author | Saiyed Tanzimjahan A. Adeyemi Jerry O. Onwudiwe Damian C. |
| author_facet | Saiyed Tanzimjahan A. Adeyemi Jerry O. Onwudiwe Damian C. |
| author_sort | Saiyed Tanzimjahan A. |
| collection | DOAJ |
| description | Dithiocarbamate complexes are of immense interest due to their diverse structural properties and extensive application in various areas. They possess two sulfur atoms that often act as the binding sites for metal coordination in a monodentate, bidentate, or anisodentate fashion. These different coordination modes enhance the possibility for complex formation and make them useful in different areas especially in biomedical fields. A synergy exists in the metal ions and dithiocarbamate moieties, which tends to exert better properties than the respective individual components of the complex. These improved properties have also been attributed to the presence of the C–S bonds. Zinc and nickel ions have been majorly found to bind to the dithiocarbamate in bidentate modes, and consequently different geometries have resulted from this interaction. The aim of this review is to present some studies on the synthesis, structural chemistry, and the relevance of zinc and nickel dithiocarbamates complexes especially in biological systems. |
| first_indexed | 2024-12-13T11:02:38Z |
| format | Article |
| id | doaj.art-2ce1ddaed507437d81307b9b76ce8966 |
| institution | Directory Open Access Journal |
| issn | 2391-5420 |
| language | English |
| last_indexed | 2024-12-13T11:02:38Z |
| publishDate | 2021-09-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Open Chemistry |
| spelling | doaj.art-2ce1ddaed507437d81307b9b76ce89662022-12-21T23:49:13ZengDe GruyterOpen Chemistry2391-54202021-09-0119197498610.1515/chem-2021-0080The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexesSaiyed Tanzimjahan A.0Adeyemi Jerry O.1Onwudiwe Damian C.2Material Science Innovation and Modelling (MaSIM) Research Focus Area, Faculty of Natural and Agricultural Science, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho, South AfricaMaterial Science Innovation and Modelling (MaSIM) Research Focus Area, Faculty of Natural and Agricultural Science, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho, South AfricaMaterial Science Innovation and Modelling (MaSIM) Research Focus Area, Faculty of Natural and Agricultural Science, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho, South AfricaDithiocarbamate complexes are of immense interest due to their diverse structural properties and extensive application in various areas. They possess two sulfur atoms that often act as the binding sites for metal coordination in a monodentate, bidentate, or anisodentate fashion. These different coordination modes enhance the possibility for complex formation and make them useful in different areas especially in biomedical fields. A synergy exists in the metal ions and dithiocarbamate moieties, which tends to exert better properties than the respective individual components of the complex. These improved properties have also been attributed to the presence of the C–S bonds. Zinc and nickel ions have been majorly found to bind to the dithiocarbamate in bidentate modes, and consequently different geometries have resulted from this interaction. The aim of this review is to present some studies on the synthesis, structural chemistry, and the relevance of zinc and nickel dithiocarbamates complexes especially in biological systems.https://doi.org/10.1515/chem-2021-0080zinc complexesnickel complexesdithiocarbamatescoordination geometrybiological application |
| spellingShingle | Saiyed Tanzimjahan A. Adeyemi Jerry O. Onwudiwe Damian C. The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes Open Chemistry zinc complexes nickel complexes dithiocarbamates coordination geometry biological application |
| title | The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes |
| title_full | The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes |
| title_fullStr | The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes |
| title_full_unstemmed | The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes |
| title_short | The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes |
| title_sort | structural chemistry of zinc ii and nickel ii dithiocarbamate complexes |
| topic | zinc complexes nickel complexes dithiocarbamates coordination geometry biological application |
| url | https://doi.org/10.1515/chem-2021-0080 |
| work_keys_str_mv | AT saiyedtanzimjahana thestructuralchemistryofzinciiandnickeliidithiocarbamatecomplexes AT adeyemijerryo thestructuralchemistryofzinciiandnickeliidithiocarbamatecomplexes AT onwudiwedamianc thestructuralchemistryofzinciiandnickeliidithiocarbamatecomplexes AT saiyedtanzimjahana structuralchemistryofzinciiandnickeliidithiocarbamatecomplexes AT adeyemijerryo structuralchemistryofzinciiandnickeliidithiocarbamatecomplexes AT onwudiwedamianc structuralchemistryofzinciiandnickeliidithiocarbamatecomplexes |