Optimisation of eggshell-zeolite composite as a potential surfactant adsorbent for hand-washing wastewater

Surfactants present in handwashing wastewater impede performance of biological treatment processes. In this study, design expert software was used to optimise a composite adsorbent from eggshells and zeolite for removal of surfactants. Percentage of eggshells in the composite, calcination time and t...

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Main Authors: Medard Turyasingura, Joel Wakatuntu, Michael Lubwama, Joseph Jjagwe, Oliver Hensel, Peter Wilberforce Olupot
Format: Article
Language:English
Published: Elsevier 2023-06-01
Series:Case Studies in Chemical and Environmental Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666016422001062
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author Medard Turyasingura
Joel Wakatuntu
Michael Lubwama
Joseph Jjagwe
Oliver Hensel
Peter Wilberforce Olupot
author_facet Medard Turyasingura
Joel Wakatuntu
Michael Lubwama
Joseph Jjagwe
Oliver Hensel
Peter Wilberforce Olupot
author_sort Medard Turyasingura
collection DOAJ
description Surfactants present in handwashing wastewater impede performance of biological treatment processes. In this study, design expert software was used to optimise a composite adsorbent from eggshells and zeolite for removal of surfactants. Percentage of eggshells in the composite, calcination time and temperature were design parameters while chemical oxygen demand (COD) was indicator for surfactants. Optimal parameters were 31.6%, 1.4h and 310.9 °C for eggshells percentage, calcination time and temperature, respectively. Resultant adsorbent had methylene blue number, surface area, pore diameter and COD removal of 95mg/g, 26m2g−1, 10nm and 88%, respectively. These parameters and nitrogen adsorption/desorption isotherms confirm effective mesoporous structured adsorbent.
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spelling doaj.art-2cfcf23a57ab4cbfbb8d0c3e80835a742023-05-08T04:09:39ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642023-06-017100284Optimisation of eggshell-zeolite composite as a potential surfactant adsorbent for hand-washing wastewaterMedard Turyasingura0Joel Wakatuntu1Michael Lubwama2Joseph Jjagwe3Oliver Hensel4Peter Wilberforce Olupot5Department of Mechanical Engineering, College of Engineering, Design, Art and Technology, Makerere University, P.O. Box 7062, Kampala, UgandaDepartment of Mechanical Engineering, College of Engineering, Design, Art and Technology, Makerere University, P.O. Box 7062, Kampala, UgandaDepartment of Mechanical Engineering, College of Engineering, Design, Art and Technology, Makerere University, P.O. Box 7062, Kampala, UgandaDepartment of Mechanical Engineering, College of Engineering, Design, Art and Technology, Makerere University, P.O. Box 7062, Kampala, UgandaDepartment of Agricultural and Biosystems Engineering, Faculty of Organic Agricultural Sciences, University of Kassel, Nordbahnhofstr. 1a, 37213, Witzenhausen, GermanyDepartment of Mechanical Engineering, College of Engineering, Design, Art and Technology, Makerere University, P.O. Box 7062, Kampala, Uganda; Corresponding author.Surfactants present in handwashing wastewater impede performance of biological treatment processes. In this study, design expert software was used to optimise a composite adsorbent from eggshells and zeolite for removal of surfactants. Percentage of eggshells in the composite, calcination time and temperature were design parameters while chemical oxygen demand (COD) was indicator for surfactants. Optimal parameters were 31.6%, 1.4h and 310.9 °C for eggshells percentage, calcination time and temperature, respectively. Resultant adsorbent had methylene blue number, surface area, pore diameter and COD removal of 95mg/g, 26m2g−1, 10nm and 88%, respectively. These parameters and nitrogen adsorption/desorption isotherms confirm effective mesoporous structured adsorbent.http://www.sciencedirect.com/science/article/pii/S2666016422001062Zeolite-eggshell compositeBox-behnken designOptimizationHandwashing wastewater treatmentSurfactant adsorption
spellingShingle Medard Turyasingura
Joel Wakatuntu
Michael Lubwama
Joseph Jjagwe
Oliver Hensel
Peter Wilberforce Olupot
Optimisation of eggshell-zeolite composite as a potential surfactant adsorbent for hand-washing wastewater
Case Studies in Chemical and Environmental Engineering
Zeolite-eggshell composite
Box-behnken design
Optimization
Handwashing wastewater treatment
Surfactant adsorption
title Optimisation of eggshell-zeolite composite as a potential surfactant adsorbent for hand-washing wastewater
title_full Optimisation of eggshell-zeolite composite as a potential surfactant adsorbent for hand-washing wastewater
title_fullStr Optimisation of eggshell-zeolite composite as a potential surfactant adsorbent for hand-washing wastewater
title_full_unstemmed Optimisation of eggshell-zeolite composite as a potential surfactant adsorbent for hand-washing wastewater
title_short Optimisation of eggshell-zeolite composite as a potential surfactant adsorbent for hand-washing wastewater
title_sort optimisation of eggshell zeolite composite as a potential surfactant adsorbent for hand washing wastewater
topic Zeolite-eggshell composite
Box-behnken design
Optimization
Handwashing wastewater treatment
Surfactant adsorption
url http://www.sciencedirect.com/science/article/pii/S2666016422001062
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